9-azido-9H-fluorene

Base Information

• Chemical Name: 9-azido-9H-fluorene
• CAS No.: 24040-37-7
• Molecular Formula: C13H9 N3
• Molecular Weight: 207.235
• NSC Number: 88983
• DSSTox Substance ID: DTXSID40402009
• Nikkaji Number: J3.644.726E
• Wikidata: Q82205353
• Mol file: 24040-37-7.mol

Synonyms:9-azido-9H-fluorene;24040-37-7;9-azido-fluorene;NCIOpen2_005608;9-fluorenyl azide;9H-Fluorene-9-yl azide;SCHEMBL14537425;DTXSID40402009;POJUGTQVVISLBM-UHFFFAOYSA-N;NSC88983;NSC-88983;AKOS010631532;J3.644.726E;EN300-179215

Chemical Property of 9-azido-9H-fluorene

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 207.079647300
• Heavy Atom Count: 16
• Complexity: 286

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C(C3=CC=CC=C32)N=[N+]=[N-]

Technology Process of 9-azido-9H-fluorene

There total 6 articles about 9-azido-9H-fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

9H-fluoren-9-yl bromide (1940-57-4) → 9-azido-9H-fluorene (24040-37-7)

Guidance literature:

With sodium azide; In water; acetone;

Reference yield: 85.0%

9-Fluorenol (1689-64-1) → 9-azido-9H-fluorene (24040-37-7)

Guidance literature:

With [Bmim]Cl-ZnCl₂; trimethylsilylazide; In dichloromethane; at 20 ℃; for 0.416667h; Inert atmosphere; Green chemistry;

DOI:10.1016/j.tetlet.2017.05.046

Reference yield:

9-Fluorenol (1689-64-1) → phenanthridine (229-87-8) + 9-azido-9H-fluorene (24040-37-7)

Guidance literature:

With sodium azide; chloroform; sulfuric acid;

DOI:10.1039/jr9530000178

upstream raw materials:

9-Fluorenol

9-chlorofluorene

9H-fluoren-9-yl bromide

Downstream raw materials:

9-diazofluorenone

phenanthridine

9-fluorenone

Refernces

• 1、 Ochmann, Lukas,Kessler, Mika L.,Schreiner, Peter R.. "Alkylphosphinites as Synthons for Stabilized Carbocations". supporting information. p. 1460 - 1464. Retrieved 2022/03/01.
• 2、 Singh, Ashima,Singh, Harjinder,Khurana. "Recyclable zinc (II) ionic liquid catalyzed synthesis of azides by direct azidation of alcohols using trimethylsilylazide at room temperature". supporting information. p. 2498 - 2502. Retrieved 2017/05/31.