9-Chlorofluorene

Base Information

• Chemical Name: 9-Chlorofluorene
• CAS No.: 6630-65-5
• Molecular Formula: C13H9 Cl
• Molecular Weight: 200.667
• Hs Code.: 2903999090
• European Community (EC) Number: 809-619-8
• NSC Number: 59976
• UNII: 2T329HG6ZB
• DSSTox Substance ID: DTXSID70216515
• Nikkaji Number: J15.117C
• Wikidata: Q83092745
• Mol file: 6630-65-5.mol

Synonyms:9-Chlorofluorene;9-Chloro-9H-fluorene;6630-65-5;9H-Fluorene, 9-chloro-;FLUORENE, 9-CHLORO-;NSC 59976;BRN 1949416;2T329HG6ZB;MFCD00043468;NSC-59976;4-05-00-02146 (Beilstein Handbook Reference);9-Chlor-fluoren;NSC59976;9-Chloro-9H-fluorene #;UNII-2T329HG6ZB;9-Chlorofluorene, AldrichCPR;ghl.PD_Mitscher_leg0.1300;SCHEMBL5343918;DTXSID70216515;BBL100169;STL227875;AKOS002663673;LS-69249;MS-20188;FT-0621636;EN300-110902

Chemical Property of 9-Chlorofluorene

Chemical Property:

• Vapor Pressure: 0.000537mmHg at 25°C
• Melting Point: 86-88℃
• Boiling Point: 322.1°C at 760 mmHg
• Flash Point: 129.9°C
• PSA: 0.00000
• Density: 1.25g/cm³
• LogP: 3.99520
• Storage Temp.: Refrigerator
• Solubility.: Chloroform (Slightly), Methanol (Slightly)
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 200.0392780
• Heavy Atom Count: 14
• Complexity: 191

Purity/Quality:

99% ^*data from raw suppliers

9-Chlorofluorene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C(C3=CC=CC=C32)Cl
• Uses: 9-Chlorofluorene is a monochlorinated fluorene with therapeutic effects on fungal diseases of tomato. 9-Chlorofluorene is part of a class of halogenated pollutants observed in the urban atmosphere.

Technology Process of 9-Chlorofluorene

There total 4 articles about 9-Chlorofluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

9-Fluorenol (1689-64-1) → 9H-fluorene (86-73-7) + 9-chlorofluorene (6630-65-5)

Guidance literature:

9-Fluorenol; With n-butyllithium; In dichloromethane; at 0 ℃;

With dichloroborane; In dichloromethane; at 0 - 20 ℃;

DOI:10.1016/j.tetlet.2009.12.018

Reference yield: 37.0%

tetrachloromethane (56-23-5) + fluoren-9-ylidene-hydrazine (13629-22-6) → 9-fluorenone (486-25-9,952573-42-1) + tetrabenzo[5.5]fulvalene (746-47-4) + 9-chlorofluorene (6630-65-5) + 9-(dichloromethylene)fluorene (835-17-6)

Guidance literature:

With ammonia; copper(l) chloride; In water; dimethyl sulfoxide; at 20 ℃;

DOI:10.1023/A:1023499925287

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + 9-acetoxy-9H-fluorene (25017-68-9) + methylammonium carbonate (15719-64-9,15719-76-3,97762-63-5) → 9-Fluorenol (1689-64-1) + 9-chlorofluorene (6630-65-5)

Guidance literature:

upstream raw materials:

1-(9H-Fluoren-9-yl)-pyridinium; chloride

hydrogenchloride

9-acetoxy-9H-fluorene

methylammonium carbonate

Downstream raw materials:

9,9'-bifluorenyl

9H-fluorene-9-carboxylic acid

1,1,2,2-tetraphenylethane

9-(diphenylmethyl)fluorene