Germane, acetoxytrimethyl-

Base Information

• Chemical Name: Germane, acetoxytrimethyl-
• CAS No.: 1118-13-4
• Molecular Formula: C5H12 Ge O2
• Molecular Weight: 176.739
• DSSTox Substance ID: DTXSID50149736
• Wikidata: Q83015602
• Mol file: 1118-13-4.mol

Synonyms:Germane, acetoxytrimethyl-;1118-13-4;Acetoxytrimethylgermane;(Acetyloxy)trimethylgermane;Germane, (acetyloxy)trimethyl-;BRN 4125624;trimethylgermanium acetate;DTXSID50149736

Chemical Property of Germane, acetoxytrimethyl-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 178.0049074
• Heavy Atom Count: 8
• Complexity: 93.1

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)O[Ge](C)(C)C

Technology Process of Germane, acetoxytrimethyl-

There total 3 articles about Germane, acetoxytrimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(methyl)3GeSn(methyl)3 (16393-89-8) → ((CH3)2SnOCOCH3)2 (97778-06-8) + tetramethylstannane (594-27-4) + dimethyltin bis(acetate) (13293-57-7) + Trimethyl-germanium-acetat (1118-13-4) + trimethyltin acetate (1118-14-5)

Guidance literature:

With acetic acid; In acetic acid; stannane was added to AcOH in a NMR tube, mixt. was kept for 20 d, reaction followed by (1)H NMR spectroscopy; ca. 29% of the substrate was consumed, rate const. for the initial 5-10% reaction (first 2 d) when only Me3SnOAc and Me3GeOAc were formed; not isolated, identified by (1)H NMR spectrum; Kinetics;

DOI:10.1016/0022-328X(85)80064-4

Reference yield:

fc-CH2-Ge(CH3)3 → methyl ferrocene + Trimethyl-germanium-acetat (1118-13-4)

Guidance literature:

With CH₃COOH; In acetic acid; solvolysis, 140°C;

DOI:10.1016/S0022-328X(00)80650-6

Reference yield:

→ Trimethyl-germanium-acetat (1118-13-4)

Guidance literature:

Chlor-trimethyl-german, wss. Kaliumacetat, W.-bad;

upstream raw materials:

(methyl)3GeSn(methyl)3