Stannane, trimethyl(trimethylgermyl)-

Base Information

• Chemical Name: Stannane, trimethyl(trimethylgermyl)-
• CAS No.: 16393-89-8
• Molecular Formula: C6H18 Ge Sn
• Molecular Weight: 281.509
• Mol file: 16393-89-8.mol

Synonyms:Stannane, trimethyl(trimethylgermyl)-;16393-89-8;(trimethylgermyl)trimet hylstannane;Germane, trimethyl(trimethylstannyl)-

Chemical Property of Stannane, trimethyl(trimethylgermyl)-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 283.964231
• Heavy Atom Count: 8
• Complexity: 30

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Ge](C)C.C[Sn](C)C

Technology Process of Stannane, trimethyl(trimethylgermyl)-

There total 1 articles about Stannane, trimethyl(trimethylgermyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

phenyltrimethylgermane (1626-00-2) + lithium trimethylstannyl (17946-71-3) → trimethyl(phenyl)stannane (934-56-5) + hexamethyldistannane (661-69-8) + hexamethyldigermane (993-52-2) + (methyl)3GeSn(methyl)3 (16393-89-8) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

In tetrahydrofuran; LiSnMe3 added to PhGeMe3 in THF, stirred at 24°C for 1 h or 50°C for 30 min, hydrolysis with water; org. layer extd. with ether, dried over Na2SO4; products isolated by preparative by GLC;

DOI:10.1246/bcsj.60.3299

Reference yield: 56.0%

bis(cycloocta-1,5-diene)platinum(0) (12130-66-4) + (methyl)3GeSn(methyl)3 (16393-89-8) + Dimethyl(phenyl)phosphine (672-66-2) → cis-[Pt(trimethylgermyl)(trimethylstannyl)(dimethylphenylphosphine)2] + trans-[Pt(trimethylgermyl)(trimethylstannyl)(dimethylphenylphosphine)2]

Guidance literature:

In diethyl ether; under N2 atm. using Schlenk techniques; to suspn. of Pt(cod)2 in Et2O added PMe2Ph and Me3GeSnMe3 at room temp.; mixt. stirred for 10 min; monitored by (31)P NMR; solvent removed; cooled to -78°C; dissolved in Et2O; pentane slowly added with vigorous stirring; solid collectedby filtration; washed (pentane); dried (vac.); recrystd. (CH2Cl2/pentan e); elem. anal.;

DOI:10.1246/bcsj.77.1287

Reference yield:

iodotrifluoromethane (2314-97-8,263005-66-9) + (methyl)3GeSn(methyl)3 (16393-89-8) → tetramethylstannane (594-27-4)

Guidance literature:

In cyclohexane; 96 h, 210°C;

DOI:10.1021/ic50101a004

upstream raw materials:

phenyltrimethylgermane

lithium trimethylstannyl

Downstream raw materials:

tetramethylstannane

((CH₃)2SnOCOCH₃)2

dimethyltin bis(acetate)

Trimethyl-germanium-acetat