(E)-Tetradec-7-enyl acetate

Base Information

• Chemical Name: (E)-Tetradec-7-enyl acetate
• CAS No.: 28540-79-6
• Molecular Formula: C16H30 O2
• Molecular Weight: 254.413
• European Community (EC) Number: 249-072-7
• DSSTox Substance ID: DTXSID001311634
• Nikkaji Number: J250.731E,J891.993C
• Metabolomics Workbench ID: 3935
• Mol file: 28540-79-6.mol

Synonyms:(E)-Tetradec-7-enyl acetate;7E-Tetradecenyl acetate;28540-79-6;(E)-7-tetradecenyl acetate;EINECS 249-072-7;AI3-33931;[(E)-tetradec-7-enyl] acetate;E-7-Tetradecen-1-ol acetate;SCHEMBL593574;SCHEMBL830443;Z-7-Tetradecen-1-ol acetate;Acetic acid 7-tetradecenyl ester;(7E)-7-Tetradecenyl acetate #;CHEBI:179810;UEZQOSGCHCNWOE-CMDGGOBGSA-N;DTXSID001311634;LMFA07010290;7-Tetradecen-1-ol, acetate, (E)-;7-Tetradecen-1-ol,1-acetate, (7Z)-;Acetic acid [(E)-7-tetradecen-1-yl] ester

Chemical Property of (E)-Tetradec-7-enyl acetate

Chemical Property:

• Vapor Pressure: 0.000136mmHg at 25°C
• Boiling Point: 333.5°Cat760mmHg
• Flash Point: 98.5°C
• PSA: 26.30000
• Density: 0.878g/cm³
• LogP: 5.02660
• XLogP3: 5.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 13
• Exact Mass: 254.224580195
• Heavy Atom Count: 18
• Complexity: 209

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCC=CCCCCCCOC(=O)C
• Isomeric SMILES: CCCCCC/C=C/CCCCCCOC(=O)C

Technology Process of (E)-Tetradec-7-enyl acetate

There total 23 articles about (E)-Tetradec-7-enyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(7E)-tetradec-7-en-1-ol (37011-95-3) + acetic anhydride (108-24-7) → E-7-tetradecen-1-yl acetate (28540-79-6)

Guidance literature:

With pyridine; In diethyl ether;

Reference yield: 93.0%

(7E)-tetradec-7-en-1-ol (37011-95-3) + acetyl chloride (75-36-5) → E-7-tetradecen-1-yl acetate (28540-79-6)

Guidance literature:

With pyridine; In benzene;

DOI:10.1021/jo00237a004

Reference yield:

(E)-1-phenoxy-2,7-octadiene (15972-89-1) → E-7-tetradecen-1-yl acetate (28540-79-6)

Guidance literature:

Multi-step reaction with 6 steps

1: 84 percent / Li₂CuCl₄ / tetrahydrofuran; diethyl ether / 3 h / 0 °C

2: 1.) 0.75M 9-borabicyclo<3.3.1>nonane; 2.) 3N NaOH, 26percent H₂O₂ / 1.) THF, 0 deg C, 2-3 h; 2.) 20 deg C, 2-3 h

3: PBr₃ / 1.) pyridine, hexane, 3-5 deg C, 3h; 2.) 20 deg C, 12 h

4: 1.) Mg / 1.) ether; 2.) ether; HCl

5: 90 percent / LiAlH₄ / diethyl ether

6: pyridine

With pyridine; sodium hydroxide; lithium aluminium tetrahydride; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide; phosphorus tribromide; magnesium; dilithium tetrachlorocuprate; In tetrahydrofuran; diethyl ether;

upstream raw materials:

(E)-2-(tetradec-7-en-1-yloxy)tetrahydro-2H-pyran

acetyl chloride

Tetradec-7-en-1-ol-acetat

(7E)-tetradec-7-en-1-ol