Carbamic acid, 1,2-ethanediylidenetetrakis-, tetraethyl ester

Base Information

• Chemical Name: Carbamic acid, 1,2-ethanediylidenetetrakis-, tetraethyl ester
• CAS No.: 17350-57-1
• Molecular Formula: C14H26N4O8
• Molecular Weight: 378.3782
• Hs Code.: 2924199090
• NSC Number: 105439
• UNII: I6I40EMX6D
• DSSTox Substance ID: DTXSID90169630
• Nikkaji Number: J104.490G
• Wikidata: Q83039342
• Mol file: 17350-57-1.mol

Synonyms:17350-57-1;Carbamic acid, 1,2-ethanediylidenetetrakis-, tetraethyl ester;ethyl N-[1,2,2-tris(ethoxycarbonylamino)ethyl]carbamate;I6I40EMX6D;Carbamic acid, ethanediylidenetetra-, tetraethyl ester;UNII-I6I40EMX6D;NSC 105439;NSC105439;NSC-105439;Carbamic acid, 1,2-ethanediylidenetetrakis-, tetraethylester;Carbamic acid, tetraethyl ester;DTXSID90169630;OHDLJZGTUGVLBO-UHFFFAOYSA-N;STL353340;AKOS022107754;1,1,2,2-tetrakis(ethoxycarbonylamino)ethane;Carbamic acid,2-ethanediylidenetetrakis-, tetraethyl ester;C,C',C'',C'''-Tetraethyl N,N',N'',N'''-1,2-ethanediylidenetetrakis[carbamate];CARBAMIC ACID, N,N',N'',N'''-1,2-ETHANEDIYLIDENETETRAKIS-, C,C',C'',C'''-TETRAETHYL ESTER;ethyl {7-[(ethoxycarbonyl)amino]-4,9-dioxo-3,10-dioxa-5,8-diazadodecan-6-yl}carbamate (non-preferred name)

Chemical Property of Carbamic acid, 1,2-ethanediylidenetetrakis-, tetraethyl ester

Chemical Property:

• Vapor Pressure: 4.36E-14mmHg at 25°C
• Boiling Point: 594.2°Cat760mmHg
• Flash Point: 313.1°C
• PSA: 153.32000
• Density: 1.222g/cm³
• LogP: 2.18660
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 13
• Exact Mass: 378.17506380
• Heavy Atom Count: 26
• Complexity: 392

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)NC(C(NC(=O)OCC)NC(=O)OCC)NC(=O)OCC

Technology Process of Carbamic acid, 1,2-ethanediylidenetetrakis-, tetraethyl ester

There total 6 articles about Carbamic acid, 1,2-ethanediylidenetetrakis-, tetraethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Glyoxal (131543-46-9,107-22-2) + urethane (51-79-6) → 1,1,2,2,-tetrakis(ethoxycarbonylamino)ethane (17350-57-1)

Guidance literature:

With boron trifluoride diethyl etherate; In benzene;

DOI:10.1021/jo01274a055

Reference yield:

1-acetoxy-1,2,2-tris(ethoxycarbonylamino)ethane (1013935-95-9) + urethane (51-79-6) → 1,1,2,2,-tetrakis(ethoxycarbonylamino)ethane (17350-57-1)

Guidance literature:

1-acetoxy-1,2,2-tris(ethoxycarbonylamino)ethane; urethane; at 100 - 110 ℃;

With toluene-4-sulfonic acid; at 100 - 110 ℃; for 0.333333h;

DOI:10.1134/S1070428007020261

Reference yield:

ethanol (64-17-5) → 1,1,2,2,-tetrakis(ethoxycarbonylamino)ethane (17350-57-1)

Guidance literature:

With diethyl ether;

upstream raw materials:

Glyoxal

urethane

ethanol

1-acetoxy-1,2,2-tris(ethoxycarbonylamino)ethane

Refernces

• 1、 Sizova,Sizov,Tselinskii. "Derivatives of 1,1,2,2-tetraaminoethane. Condensation of 1,2-diacetoxy-1,2-bis(ethoxycarbonylamino)ethane and 1-acetoxy-1,2,2- tris(ethoxycarbonylamino)ethane with nitrogen-containing nucleophiles". . p. 309 - 311. Retrieved 2007.