Synonyms:Phosphorothioicacid, O,O-diisopropyl O-[p-(methylsulfinyl)phenyl] ester (6CI,7CI,8CI); Bayer25142; O,O-Diisopropyl O-p-methylsulfinylphenylthiophosphate
99% *data from raw suppliers
O,O-BISISOPROPYL-O-(4-(METHYLSULFINYL)PHENYL)PHOSPHOROTHIOATE 95.00% *data from reagent suppliers
There total 1 articles about O,O-Bisisopropyl O-(4-(methylsulfinyl)phenyl) phosphorothioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
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The research details the first isolation and structural analysis of chalcogenocarboxylato samarium complexes, specifically [(RCOS)3Sm(thf)2] and [Na(thf)4][Sm(RCSS)4], where R = 4-MeC6H4. These complexes exhibit alkali metal salt-like reactions, such as S-esterification, and also undergo an insertion reaction of C=N into the Sm-S bond. The study highlights the synthesis of these complexes using reactions involving potassium thiocarboxylate and sodium 4-methylbenzenecarbodithioate with samarium chloride. The compounds were characterized using IR, 'H and 13C NMR spectra, and X-ray diffraction analysis. The research also explores the reactivity of these complexes with alkyl and allyl iodides, resulting in the formation of thioesters and dithioesters, and their reaction with 4-methylbenzoyl chloride to produce symmetrical and unsymmetrical sulfides. The study provides valuable insights into the chemistry of lanthanide chalcogenocarboxylates, which have potential relevance in understanding the bonding and function of biologically active centers in metalloproteins.
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