Chemistry Letters p. 957 - 958 (1998)
Update date:2022-09-26
Topics:
Kanda, Takahiro
Ibi, Mitsuo
Mochizuki, Ken-Ichi
Kato, Shinzi
The first chalcogenocarboxylato lanthanid complexes, [(RCOS)3Sm(thf)2] and [Na(thf)4][Sm(RCSS)4](R=4-MeC6H4) were isolated and characterized crystallographically. They exhibit an alkali metal salt-like reaction such as S-esterification and an insertion reaction of C=N to the Sm-S bond.
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