dichloroplatinum(2+) bis(2-thioxo-1,3-benzothiazol-3-ide)

Base Information

• Chemical Name: dichloroplatinum(2+) bis(2-thioxo-1,3-benzothiazol-3-ide)
• CAS No.: 57948-09-1
• Molecular Formula: C₁₄H₁₀Cl₂N₂PtS₄
• Molecular Weight: 600.497
• Mol file: 57948-09-1.mol

Synonyms:

Chemical Property of dichloroplatinum(2+) bis(2-thioxo-1,3-benzothiazol-3-ide)

Chemical Property:

• Vapor Pressure: 0.000844mmHg at 25°C
• Boiling Point: 305°Cat760mmHg
• Flash Point: 138.3°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dichloroplatinum(2+) bis(2-thioxo-1,3-benzothiazol-3-ide)

There total 2 articles about dichloroplatinum(2+) bis(2-thioxo-1,3-benzothiazol-3-ide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

potassium tetrachloroplatinate(II) (10025-99-7) + 2-Mercaptobenzothiazole (149-30-4,118090-09-8) → cis-[Pt(2-mercaptobenzothiazole)2Cl2] (122332-45-0,16998-21-3,57948-09-1,12564-56-6)

Guidance literature:

In ethanol; water; pptn. on addn. of hot aq. K2PtCl4 to 2 equiv. of ligand (in H2O/EtOH=1:1); washing (H2O, alcohol), recrystn. (DMF/Et2O); elem. anal.;

DOI:10.1016/S0020-1693(00)81954-4

Reference yield:

potassium tetrachloroplatinate(II) (10025-99-7) + 2-Mercaptobenzothiazole (149-30-4,118090-09-8) → {Pt(benzothiazoline-2-thione)2Cl2} (122332-45-0,12564-56-6,57948-09-1,16998-21-3)

Guidance literature:

In hydrogenchloride; ethanol; water; dropwise addn. of the metal salt soln. to the ligand soln. (stoich. amts.), pptn.; filtration, washing with ethanol, drying at 70°C, elem. anal.;

DOI:10.1016/0040-6031(89)87315-0

Reference yield:

{Pt(benzothiazoline-2-thione)2Cl2} (122332-45-0,12564-56-6,57948-09-1,16998-21-3) → platinum (7440-06-4)

Guidance literature:

With air; In solid; thermal decomposition in air on heating in the temp. range 0 - 475°C, stepwise mass loss up to 310°C;

DOI:10.1016/0040-6031(89)87315-0

upstream raw materials:

potassium tetrachloroplatinate(II)

2-Mercaptobenzothiazole

Downstream raw materials:

platinum