2-Anthracenesulfonyl chloride

Base Information

• Chemical Name: 2-Anthracenesulfonyl chloride
• CAS No.: 17407-98-6
• Molecular Formula: C14H9ClO2S
• Molecular Weight: 276.743
• Hs Code.: 2904909090
• European Community (EC) Number: 634-938-2
• NSC Number: 140126
• DSSTox Substance ID: DTXSID50300946
• Nikkaji Number: J82.623E
• Wikidata: Q82044400
• Mol file: 17407-98-6.mol

Synonyms:2-Anthracenesulfonyl chloride;17407-98-6;anthracene-2-sulfonyl chloride;2-Anthracenylsulfonyl chloride;Anthrazen-2-sulfochlorid;anthracene-2-sulfonylchloride;SCHEMBL1149006;DTXSID50300946;FZAQROFXYZPAKI-UHFFFAOYSA-N;BETA-NICOTINAMIDEMONONUCLEOTIDE;MFCD00467322;NSC140126;AKOS016016503;NSC-140126;FT-0611285;J-100020;2-Anthracenesulfonyl chloride, BioReagent, suitable for fluorescence, >=90.0% (HPLC)

Chemical Property of 2-Anthracenesulfonyl chloride

Chemical Property:

• Vapor Pressure: 1.77E-08mmHg at 25°C
• Melting Point: 142.5℃
• Refractive Index: 1.704
• Boiling Point: 467.8 °C at 760 mmHg
• Flash Point: 236.7 °C
• PSA: 42.52000
• Density: 1.424 g/cm³
• LogP: 5.00130
• Solubility.: acetonitrile: soluble
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 276.0011784
• Heavy Atom Count: 18
• Complexity: 401

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Anthracenesulfonyl chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C2C=C3C=C(C=CC3=CC2=C1)S(=O)(=O)Cl
• Uses: Derivatizing reagent with strong fluorescence.

Technology Process of 2-Anthracenesulfonyl chloride

There total 5 articles about 2-Anthracenesulfonyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

anthracene-2-sulfonic acid potassium salt (66601-71-6) → anthracene-2-sulfonyl chloride (17407-98-6)

Guidance literature:

With phosphorus pentachloride; at 120 ℃;

DOI:10.1021/ja207751w

Reference yield:

→ anthracene-2-sulfonyl chloride (17407-98-6)

Guidance literature:

With trichlorophosphate; phosphorus trichloride; at 120 ℃;

Reference yield:

sodium anthraquinone-2-sulfonate (131-08-8) → anthracene-2-sulfonyl chloride (17407-98-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: ammonium carbonate / water / 80 °C

1.2: 72 h / 80 °C

2.1: phosphorus pentachloride / 120 °C

With phosphorus pentachloride; ammonium carbonate; In water;

DOI:10.1021/ja207751w

upstream raw materials:

sodium anthraquinone-2-sulfonate

anthracene-2-sulfonic acid potassium salt

Downstream raw materials:

9,10-dioxo-9,10-dihydro-2-anthracenesulfonyl chloride

Refernces