Tricyclo(5.3.1.0)undeca-2,4,9-triene

Base Information

Chemical Name:Tricyclo(5.3.1.0)undeca-2,4,9-triene
CAS No.:67313-66-0
Molecular Formula:C11H12
Molecular Weight:144.213
Hs Code.:
DSSTox Substance ID:DTXSID20986574

Synonyms:Tricyclo(5.3.1.0)undeca-2,4,9-triene;Tricyclo[5.3.1.0]undeca-2,4,9-triene;67313-66-0;1H,8H-3a,8a-Methanoazulene;DTXSID20986574

Suppliers and Price of Tricyclo(5.3.1.0)undeca-2,4,9-triene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Tricyclo(5.3.1.0)undeca-2,4,9-triene

Chemical Property:

Vapor Pressure:0.0842mmHg at 25°C
Boiling Point:233.7°Cat760mmHg
Flash Point:70.8°C
Density:1.06g/cm³
XLogP3:3.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:144.093900383
Heavy Atom Count:11
Complexity:282

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C=CC=CC23C1(C2)CC=C3

Technology Process of Tricyclo(5.3.1.0)undeca-2,4,9-triene

There total 5 articles about Tricyclo(5.3.1.0)undeca-2,4,9-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 78924-86-4
Tricyclo<5.3.1.0^1,7>undeca-2,4-dien-10-one tosylhydrazone

: 67313-66-0
tricyclo[5.3.1.0^1,7]undeca-2,4,9-triene

Guidance literature:: With methyllithium; In diethyl ether; for 4h; Ambient temperature;
DOI:10.1021/ja00407a044

Reference yield:

: 52487-41-9
1,2,3,4-tetrahydroazulen-1-one

: 67313-66-0
tricyclo[5.3.1.0^1,7]undeca-2,4,9-triene

Guidance literature:: Multi-step reaction with 3 steps

1: 73 percent / NaH / dimethylsulfoxide / 1 h / 75 °C

2: 87 percent / tetrahydrofuran / 15 h / 20 °C

3: 91 percent / MeLi / diethyl ether / 1 h / 20 °C

With methyllithium; sodium hydride; In tetrahydrofuran; diethyl ether; dimethyl sulfoxide;
DOI:10.1002/1522-2675(20010516)84:5<1017::AID-HLCA1017>3.0.CO;2-L

Reference yield:

: 67313-65-9
tricyclo<5.3.1.0^1,7>undeca-2,4-dien-10-one

: 67313-66-0
tricyclo[5.3.1.0^1,7]undeca-2,4,9-triene

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / tetrahydrofuran / 15 h / 20 °C

2: 91 percent / MeLi / diethyl ether / 1 h / 20 °C

With methyllithium; In tetrahydrofuran; diethyl ether;
DOI:10.1002/1522-2675(20010516)84:5<1017::AID-HLCA1017>3.0.CO;2-L