[[2,2'-[1,2-phenylenebis(nitrilomethylidyne)]bis[phenolato]] (2-)-N,N',O,O']-Nickel

Base Information

• Chemical Name: [[2,2'-[1,2-phenylenebis(nitrilomethylidyne)]bis[phenolato]] (2-)-N,N',O,O']-Nickel
• CAS No.: 14406-71-4
• Molecular Formula: C₂₀H₁₄N₂NiO₂
• Molecular Weight: 373.033
• Mol file: 14406-71-4.mol

Synonyms:Nickel,[[2,2'-[1,2-phenylenebis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-;Nickel, [[a,a'-(o-phenylenedinitrilo)di-o-cresolato](2-)]-(6CI,7CI,8CI); Phenol, 2,2'-[1,2-phenylenebis(nitrilomethylidyne)]bis-, nickelcomplex; 2,2'-[o-Phenylenebis(nitrilomethylidyne)]diphenolnickel(II)

Chemical Property of [[2,2'-[1,2-phenylenebis(nitrilomethylidyne)]bis[phenolato]] (2-)-N,N',O,O']-Nickel

Chemical Property:

• Melting Point: 285 °C
• PSA: 24.48000
• LogP: 3.74520

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [[2,2'-[1,2-phenylenebis(nitrilomethylidyne)]bis[phenolato]] (2-)-N,N',O,O']-Nickel

There total 32 articles about [[2,2'-[1,2-phenylenebis(nitrilomethylidyne)]bis[phenolato]] (2-)-N,N',O,O']-Nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(E)-N,N'-bis(salicylidene)-1,2-phenylenediamine (3946-91-6,86328-88-3) + nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) → N,N'-o-phenylenebis(salicylideneiminato)nickel(II) (36433-88-2,14406-71-4)

Guidance literature:

In methanol; for 1h; Reflux;

DOI:10.1016/j.jinorgbio.2019.03.022

Reference yield: 92.0%

2,2′-((1E,1′E)-(1,2-phenylenebis(azanylylidene))bis(methanylylidene))diphenolzinc(II) (21380-07-4) + nickel(II) acetate tetrahydrate (6018-89-9) → N,N'-o-phenylenebis(salicylideneiminato)nickel(II) (36433-88-2,14406-71-4)

Guidance literature:

In tetrahydrofuran; Zn complex reacted with Ni acetate in THF;

DOI:10.1021/ic701245r

Reference yield: 85.0%

nickel(II) chloride hexahydrate + N,N'-bis(salicylidene)-o-phenylenediamine (3946-91-6) → N,N'-o-phenylenebis(salicylideneiminato)nickel(II) (36433-88-2,14406-71-4)

Guidance literature:

With triethylamine; for 0.333333h;

DOI:10.1016/j.poly.2016.05.064

upstream raw materials:

salicylaldehyde

1,2-diamino-benzene

nickel dichloride

N,N'-bis(salicylidene)-o-phenylenediamine

Downstream raw materials:

nickel(II) oxide

oxygen

nickel

poly[Ni(II) N,N'-bis(salicylidene)-o-phenylenediamine]