Bis(2-methoxyethyl) carbonate

Base Information

• Chemical Name: Bis(2-methoxyethyl) carbonate
• CAS No.: 626-84-6
• Molecular Formula: C₇H₁₄O₅
• Molecular Weight: 178.185
• European Community (EC) Number: 633-105-0
• NSC Number: 7314
• DSSTox Substance ID: DTXSID80978172
• Nikkaji Number: J102.656I
• Wikidata: Q82963506
• Mol file: 626-84-6.mol

Synonyms:Bis(2-methoxyethyl) carbonate;626-84-6;Carbonic acid bis(2-methoxyethyl) ester;Ethanol, 2-methoxy-, carbonate (2:1);bis(2-methoxyethyl)carbonate;SCHEMBL302273;Ethanol, 2-methoxy-, carbonate;DTXSID80978172;NSC7314;NSC 7314;NSC-7314;carbonic acid bis-(2-methoxy-ethyl ester)

Chemical Property of Bis(2-methoxyethyl) carbonate

Chemical Property:

• Vapor Pressure: 0.0639mmHg at 25°C
• Refractive Index: 1.4204 (estimate)
• Boiling Point: 231°Cat760mmHg
• Flash Point: 85.7°C
• PSA: 53.99000
• Density: 1.069g/cm³
• LogP: 0.43240
• XLogP3: 0.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 8
• Exact Mass: 178.08412354
• Heavy Atom Count: 12
• Complexity: 102

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COCCOC(=O)OCCOC

Technology Process of Bis(2-methoxyethyl) carbonate

There total 7 articles about Bis(2-methoxyethyl) carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

dibutyldimethoxytin (1067-55-6,235102-07-5) + carbonic acid dimethyl ester (616-38-6) → bis(2-methoxyethyl)carbonate (626-84-6)

Guidance literature:

In 2-methoxy-ethanol;

Reference yield: 29.6%

2-methoxy-ethanol (109-86-4,95507-80-5) + carbon monoxide (201230-82-2) → bis(2-methoxyethyl)carbonate (626-84-6)

Guidance literature:

With potassium selenite; oxygen; at 70 ℃; for 2h; under 37503.8 Torr; Catalytic behavior;

Reference yield: 29.0%

2-methoxy-ethanol (109-86-4,95507-80-5) + carbonic acid dimethyl ester (616-38-6) → bis(2-methoxyethyl)carbonate (626-84-6)

Guidance literature:

With sodium methylate; Reflux;

DOI:10.1016/j.ica.2013.03.018

upstream raw materials:

phosgene

2-methoxy-ethanol

bis(trichloromethyl) carbonate

potassium methoxyethyl monothiocarbonate

Downstream raw materials:

C₁₅H₂₂N₂O₆

Refernces

• 1、 Klepalová, Iva,Honzí?ek, Jan,Vinklárek, Jaromír,Padělková, Zdeňka,?ebestová, Lucie,?ezá?ová, Martina. "Vanadocene and niobocene dihalides containing electron-withdrawing substituents in the cyclopentadienyl rings: Synthesis, characterization and cytotoxicity". . p. 109 - 115. Retrieved 2013/07/27.
• 2、 -. "Decarboxylation processes using mixed metal oxide catalysts". . . Retrieved 2008/06/13.