(E,Z)-Perfluoro-2,4-hexadiene

Base Information

• Chemical Name: (E,Z)-Perfluoro-2,4-hexadiene
• CAS No.: 83168-66-5
• Molecular Formula: C6F10
• Molecular Weight: 262.0482
• Hs Code.: 2903399090
• DSSTox Substance ID: DTXSID401021592
• Mol file: 83168-66-5.mol

Synonyms:(E,Z)-Perfluoro-2,4-hexadiene;83168-66-5;(E,Z)-(CF3CF=CF)2;DTXSID401021592;(2E,4Z)-Perfluoro-2,4-hexadiene

Chemical Property of (E,Z)-Perfluoro-2,4-hexadiene

Chemical Property:

• Vapor Pressure: 38.8mmHg at 25°C
• Boiling Point: 102.5°Cat760mmHg
• Flash Point: 17.1°C
• PSA: 0.00000
• Density: 1.554g/cm³
• LogP: 4.41220
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 1
• Exact Mass: 261.98403162
• Heavy Atom Count: 16
• Complexity: 292

Purity/Quality:

99%+ ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=C(C(F)(F)F)F)(C(=C(C(F)(F)F)F)F)F
• Isomeric SMILES: C(=C(/C(F)(F)F)\F)(\C(=C(/C(F)(F)F)\F)\F)/F

Technology Process of (E,Z)-Perfluoro-2,4-hexadiene

There total 5 articles about (E,Z)-Perfluoro-2,4-hexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

perfluoroallyl iodide (431-65-2) → (E,Z)-perfluoro-2,4-hexadiene (83168-66-5) + trans,trans-Perfluoro-2,4-hexadiene (83168-67-6) + (Z,Z)-perfluoro-2,4-hexadiene (83168-65-4)

Guidance literature:

With tetracarbonyl nickel; In acetonitrile; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/jo970805y

Reference yield:

perfluoropropenylcopper (102682-88-2,102682-89-3) + (Z)-perfluoropropenyl iodide (102682-82-6) → (E,Z)-perfluoro-2,4-hexadiene (83168-66-5)

Guidance literature:

DOI:10.1021/ja00235a032

Reference yield:

perfluoro-cis-3,4-dimethylcyclobutene (89031-87-8) → (E,Z)-perfluoro-2,4-hexadiene (83168-66-5)

Guidance literature:

at 207.8 ℃; Thermodynamic data; ΔH(excit.), ΔS(excit.), ΔG(excit.);

DOI:10.1021/ja00235a032

upstream raw materials:

Perfluoro-1,5-hexadiene

perfluoropropenylcopper

(Z)-perfluoropropenyl iodide

perfluoro-cis-3,4-dimethylcyclobutene