(Bromomethyl)(triphenyl)silane

Base Information

Chemical Name:(Bromomethyl)(triphenyl)silane
CAS No.:18670-61-6
Molecular Formula:C19H17BrSi
Molecular Weight:353.33
Hs Code.:
NSC Number:179704
DSSTox Substance ID:DTXSID70306768
Nikkaji Number:J651.091D
Wikidata:Q82054048

Synonyms:18670-61-6;(Bromomethyl)(triphenyl)silane;NSC179704;bromomethyltriphenylsilane;DTXSID70306768;NSC-179704

Suppliers and Price of (Bromomethyl)(triphenyl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 9 raw suppliers

Chemical Property of (Bromomethyl)(triphenyl)silane

Chemical Property:

Vapor Pressure:5.84E-06mmHg at 25°C
Refractive Index:1.623
Boiling Point:390.7 °C at 760 mmHg
Flash Point:287.2 °C
Density:1.28 g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:4
Exact Mass:352.02829
Heavy Atom Count:21
Complexity:253

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)[Si](CBr)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of (Bromomethyl)(triphenyl)silane

There total 6 articles about (Bromomethyl)(triphenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 15409-72-0
(dibromomethyl)triphenylsilane

: 18670-61-6
Bromo(triphenylsilyl)methane

Guidance literature:: (dibromomethyl)triphenylsilane; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 0.166667h;

With hydrogen bromide; In diethyl ether; hexane; at -78 - 20 ℃; Further stages.;
DOI:10.1021/jo010471j

Reference yield: 36.0%

: 75-25-2
Bromoform

: 76-86-8
Triphenylsilyl chloride

: 18670-61-6
Bromo(triphenylsilyl)methane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; pentane; for 56h; Ambient temperature;

Reference yield:

: 789-25-3
HSiPh₃

: 18670-61-6
Bromo(triphenylsilyl)methane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 30 percent / benzene / 4 h / 85 °C

2.1: n-BuLi / diethyl ether; hexane / 0.17 h / -78 °C

2.2: 44 percent / HBr gas / diethyl ether; hexane / -78 - 20 °C

With n-butyllithium; In diethyl ether; hexane; benzene;
DOI:10.1021/jo010471j