1,3-BUTADIENE (1,1,4,4-D4)

Base Information

• Chemical Name: 1,3-BUTADIENE (1,1,4,4-D4)
• CAS No.: 10545-58-1
• Molecular Formula: C4H2 D4
• Molecular Weight: 54.09
• Mol file: 10545-58-1.mol

Synonyms:1,1,4,4-Tetradeuteriobutadiene;1,1,4,4-Tetradeuterobutadiene; Butadiene-1,1,4,4-d4; [1,1,4,4-D4]Buta-1,3-diene

Chemical Property of 1,3-BUTADIENE (1,1,4,4-D4)

Chemical Property:

• Melting Point: 49.5-50.5 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 0.638 g/cm³
• LogP: 1.35840

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,3-Butadiene-1,1,4,4-d4(gas) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-BUTADIENE (1,1,4,4-D4)

There total 4 articles about 1,3-BUTADIENE (1,1,4,4-D4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2,5,5-tetradeuteriated-2,5-dihydrothiophene 1,1-dioxide (20966-34-1) → 1,1,4,4-tetradeuterio-1,3-butadiene (10545-58-1)

Guidance literature:

at 180 ℃;

DOI:10.1021/ma034013j

Reference yield:

3-Sulfolene (77-79-2) → 1,1,4,4-tetradeuterio-1,3-butadiene (10545-58-1)

Guidance literature:

With water-d2; potassium carbonate; Multistep reaction; 1.) dioxane, RT, 96 h, 2.) 150 deg C, 1.5 h;

DOI:10.1021/jo00361a031

Reference yield:

2,2,4,4-tetradeuterobicyclo<1.1.0>butane (64435-33-2) → 1,1,4,4-tetradeuterio-1,3-butadiene (10545-58-1) + 1,1,3,4-TETRA-DEUTEROBUTADIENE + C4H2(2)H4

Guidance literature:

In cyclohexane; Product distribution; Mechanism; Irradiation;

DOI:10.1021/ja00290a063

upstream raw materials:

3-Sulfolene

2,2,4,4-tetradeuterobicyclo<1.1.0>butane

2,2,5,5-tetradeuteriated-2,5-dihydrothiophene 1,1-dioxide

Downstream raw materials:

C₇H₄⁽²⁾H₄F₃NO₂

Refernces

• 1、 Mueller,P. et al.. "". . p. 2081 - 2087. Retrieved 1978.
• 2、 DiFrancesco, Dale,Pinhas, Allan R.. "The Nickel Promoted 1,3-Migration of an sp2 Center: Ring Expansion of a Vinylcyclobutene". . p. 2098 - 2102. Retrieved 2007/10/02.