Chromium(1+),dichlorobis(1,2-ethanediamine-kN,kN')-, chloride, (OC-6-22)- (9CI)

Base Information

• Chemical Name: Chromium(1+),dichlorobis(1,2-ethanediamine-kN,kN')-, chloride, (OC-6-22)- (9CI)
• CAS No.: 14240-29-0
• Molecular Formula: C₄H₁₆Cl₂CrN₄*Cl
• Molecular Weight: 278.553
• Mol file: 14240-29-0.mol

Synonyms:Chromium(1+),dichlorobis(1,2-ethanediamine-N,N')-, chloride, (OC-6-22)-; Chromium(1+),dichlorobis(ethylenediamine)-, chloride, cis- (8CI); NSC 187633;cis-Dichlorobis(ethylenediamine)chromium(1+) chloride;cis-Dichlorobis(ethylenediamine)chromium(1+) monochloride

Chemical Property of Chromium(1+),dichlorobis(1,2-ethanediamine-kN,kN')-, chloride, (OC-6-22)- (9CI)

Chemical Property:

• Boiling Point: 119.7°Cat760mmHg
• Flash Point: 33.9°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Chromium(1+),dichlorobis(1,2-ethanediamine-kN,kN')-, chloride, (OC-6-22)- (9CI)

There total 6 articles about Chromium(1+),dichlorobis(1,2-ethanediamine-kN,kN')-, chloride, (OC-6-22)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-[chromium(1,2-diaminoethane)2Cl2]Cl → trans-{CrCl2(C2H4(NH2)2)2}Cl (14240-29-0,14301-97-4,59109-96-5,66653-37-0)

Guidance literature:

In methanol; spectrophotometric investigation of cis-trans-isomerization in almost anhydrous methanol (H2O-content < 0.04 mol/l) at 50 °C;; Kinetics;

DOI:10.1021/j150577a603

Reference yield:

tris(ethylenediamine)chromium(III) chloride * 3.5H2O (16165-32-5) → cis-[Cr(ethylenediamine)2Cl2]Cl (14240-29-0,14301-97-4,59109-96-5,66653-37-0)

Guidance literature:

In ethanol; byproducts: NH2CH2CH2NH2; Kinetics;

DOI:10.1016/0022-1902(80)80383-6

Reference yield:

trans-dichlorobis(ethylenediamine)chromium(III) chloride * HCl *2H2O → trans-{CrCl2(C2H4(NH2)2)2}Cl (14240-29-0,14301-97-4,59109-96-5,66653-37-0)

Guidance literature:

In neat (no solvent); heating trans-(CrCl2(C2H8N2)Cl*HCl*2H2O at 90 °C in vac.; exclusion of light;;

DOI:10.1021/j150577a603

upstream raw materials:

tris(ethylenediamine)chromium(III) chloride * xH₂O

hydrogenchloride

water

tris(ethylenediamine)chromium(III) chloride * 3.5H2O

Downstream raw materials:

d-{Cren3}(3+)

Refernces

• 1、 Metcalf, Lawrence E.,House, J. E. Jr.. "". . p. 961 - 964. Retrieved 1980.
• 2、 Mainusch, Bernadette,Karocki,Guldi,Stasicka,Wasgestian. "Charge transfer photochemistry of Reinecke's salt and of some of its analogues containing organic amines". . p. 87 - 93. Retrieved 2008/10/08.