manganese(2+) tetrafluoroborate(1-)

Base Information

• Chemical Name: manganese(2+) tetrafluoroborate(1-)
• CAS No.: 30744-82-2
• Molecular Formula: BF4 . 1/2 Mn
• Molecular Weight: 228.547
• Mol file: 30744-82-2.mol

Synonyms:Borate(1-),tetrafluoro-, manganese(2+) (8CI); Manganese tetrafluoroborate (7CI); Manganesebis(tetrafluoroborate); Manganese borofluoride; Manganese(2+)bis(tetrafluoroborate); Manganese(II) tetrafluoroborate

Chemical Property of manganese(2+) tetrafluoroborate(1-)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.30000

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of manganese(2+) tetrafluoroborate(1-)

There total 2 articles about manganese(2+) tetrafluoroborate(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hexacarbonylmanganese(I) tetrafluoroborate (15557-71-8) → manganese(II) tetrafluoroborate (30744-82-2) + dimanganese decacarbonyl (10170-69-1) + carbon monoxide (201230-82-2)

Guidance literature:

In neat (no solvent); 170°C, vac. line;

DOI:10.1021/ic700798z

Reference yield:

manganese (7439-96-5) → manganese(II) tetrafluoroborate (30744-82-2)

Guidance literature:

With BF₃; In hydrogen fluoride; byproducts: H2; HF (liquid); weighing cleaned Mn into a Kel-F tube, evacuating, distilling (vac.) anhydrous HF onto the metal, then gaseous BF3 at ca. 200 kPa overpressure (precaution against corrosion of the metal fittings!); periodically removing H2 by freezing in liq. N2 and pumping (--> clear soln.); spectroscopic identification;

upstream raw materials:

hexacarbonylmanganese(I) tetrafluoroborate

manganese

Refernces

• 1、 Cockman, Russell W.,Hoskins, Bernard F.,McCormick, Malcolm J.,O'Donnell, Thomas A.. "Isolation and crystal structure of manganese(II) tetrafluoroborate: A unique example of manganese(II) with seven unidentate ligands". . p. 2742 - 2745. Retrieved 2008/10/08.