triphenylsilyl hydroperoxide

Base Information

• Chemical Name: triphenylsilyl hydroperoxide
• CAS No.: 2319-38-2
• Molecular Formula: C18H16 O2 Si
• Molecular Weight: 292.409
• Mol file: 2319-38-2.mol

Synonyms:Hydroperoxytriphenylsilane;NSC 146122; Triphenylsilicon hydroperoxide; Triphenylsilyl hydroperoxide

Chemical Property of triphenylsilyl hydroperoxide

Chemical Property:

• Vapor Pressure: 3.26E-07mmHg at 25°C
• Boiling Point: 402.8°Cat760mmHg
• Flash Point: 197.4°C
• Density: 1.17g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of triphenylsilyl hydroperoxide

There total 4 articles about triphenylsilyl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

Triphenylsilyl chloride (76-86-8) → triphenylsilyl hydroperoxide (2319-38-2)

Guidance literature:

With ammonia; dihydrogen peroxide; In diethyl ether; at 0 ℃; for 0.1h;

DOI:10.1039/c9ce01882d

Reference yield:

1,1,1-triphenylsilylamine (4215-80-9) → triphenylsilyl hydroperoxide (2319-38-2)

Guidance literature:

With dihydrogen peroxide; In diethyl ether;

DOI:10.1021/jo01018a075

Reference yield:

Triphenylsilyl chloride (76-86-8) → triphenylsilyl hydroperoxide (2319-38-2)

Guidance literature:

Multi-step reaction with 2 steps

1: NH₃ / diethyl ether / Heating

2: H₂O₂ / diethyl ether

With ammonia; dihydrogen peroxide; In diethyl ether;

DOI:10.1021/jo01018a075

upstream raw materials:

Triphenylsilyl chloride

1,1,1-triphenylsilylamine

Downstream raw materials:

{(C₆H₅)3SbOSi(C₆H₅)3}2O

butyric acid

butan-1-ol

phenol