1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-

Base Information

• Chemical Name: 1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-
• CAS No.: 28075-50-5
• Molecular Formula: C7H9 F3 O3 S
• Molecular Weight: 230.208
• Hs Code.: 2906199090
• Mol file: 28075-50-5.mol

Synonyms:Methanesulfonicacid, trifluoro-, 1-cyclohexen-1-yl ester (8CI,9CI); 1-Cyclohexen-1-ol, trifluoromethanesulfonate(8CI); 1-Cyclohexen-1-yl triflate; 1-Cyclohexenyl triflate; Cyclohex-1-en-1-yltrifluoromethanesulfonate; Cyclohex-1-enyl trifluoromethanesulfonate;Cyclohexanone enol triflate; NSC 263694; Trifluoromethanesulfonic acidcyclohex-1-enyl ester

Chemical Property of 1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-

Chemical Property:

• Vapor Pressure: 0.047mmHg at 25°C
• Boiling Point: 244.6°Cat760mmHg
• Flash Point: 101.7°C
• PSA: 51.75000
• Density: 1.42g/cm³
• LogP: 3.39130
• Storage Temp.: 2-8°C

Purity/Quality:

98% ^*data from raw suppliers

Cyclohex-1-en-1-ylTrifluoromethanesulfonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Cyclohex-1-en-1-yl Trifluoromethanesulfonate is used a reactant in the regioselective preparation of phenylpyrrolidines via C-H functionalization of amines with aryl halides.

Technology Process of 1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-

There total 12 articles about 1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

N,N-phenylbistrifluoromethane-sulfonimide (37595-74-7) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → cyclohex-1-en-1-yl trifluoromethane sulfonate (28075-50-5)

Guidance literature:

cyclohexanone; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;

N,N-phenylbistrifluoromethane-sulfonimide; In tetrahydrofuran; at -78 - 20 ℃; for 16h; Inert atmosphere;

DOI:10.1002/cjoc.201900035

Reference yield: 95.0%

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + (CF3SO2)2NC6H4-O-(PEG-3400)-OC6H4N(SO2CF3)2 → cyclohex-1-en-1-yl trifluoromethane sulfonate (28075-50-5)

Guidance literature:

cyclohexanone; With lithium diisopropyl amide; In tetrahydrofuran; 1,2-dimethoxyethane; at -78 ℃; for 2h;

(CF₃SO₂)2NC₆H₄-O-(PEG-3400)-OC₆H₄N(SO₂CF₃)2; In tetrahydrofuran; 1,2-dimethoxyethane; at 0 ℃; for 8h; Further stages.;

DOI:10.1021/ol9913237

Reference yield: 89.0%

trifluoromethylsulfonic anhydride (358-23-6) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → cyclohex-1-en-1-yl trifluoromethane sulfonate (28075-50-5)

Guidance literature:

With sodium carbonate; In dichloromethane; for 24h; Ambient temperature;

upstream raw materials:

trifluoromethylsulfonic anhydride

cyclohexanone

N,N-phenylbistrifluoromethane-sulfonimide

phenyl trifluoromethanesulfonamide

Downstream raw materials:

(R)-2-cyclohex-1'-en-1'-yl-2,3-dihydrofuran

1-(1-butoxyethenyl)cyclohexene

4-(1'-Cyclohexenyl)-4-butanolide

Cyclohex-1-enecarboxylic acid ((S)-1-hydroxymethyl-2-methyl-propyl)-amide

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 28075-50-5 1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-

Send

Send

Metric Ton KG G Pound L ML

Send

Send