2-Methoxyethyl 2-cyanoacrylate

Base Information

• Chemical Name: 2-Methoxyethyl 2-cyanoacrylate
• CAS No.: 27816-23-5
• Molecular Formula: C7H9 N O3
• Molecular Weight: 155.153
• Hs Code.: 2926909090
• European Community (EC) Number: 248-670-5
• UNII: E6N1APF30P
• DSSTox Substance ID: DTXSID0067341
• Nikkaji Number: J250.592D
• Wikidata: Q81993918
• Mol file: 27816-23-5.mol

Synonyms:2-Methoxyethyl 2-cyanoacrylate;27816-23-5;2-Propenoic acid, 2-cyano-, 2-methoxyethyl ester;2-methoxyethyl 2-cyanoprop-2-enoate;METHOXYETHYL CYANOACRYLATE;E6N1APF30P;EINECS 248-670-5;EC 248-670-5;MXBON MECA MONOMER;UNII-E6N1APF30P;2-Methoxyethyl2-cyanoacrylate;SCHEMBL487323;DTXSID0067341;2-Cyanoacrylic acid 2-methoxyethyl ester;METHOXYETHYL CYANOACRYLATE [INCI];E83794

Chemical Property of 2-Methoxyethyl 2-cyanoacrylate

Chemical Property:

• Vapor Pressure: 0.0312mmHg at 25°C
• Boiling Point: 243.9°Cat760mmHg
• Flash Point: 102.7°C
• PSA: 59.32000
• Density: 1.091g/cm³
• LogP: 0.25578
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 155.058243149
• Heavy Atom Count: 11
• Complexity: 201

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COCCOC(=O)C(=C)C#N

Technology Process of 2-Methoxyethyl 2-cyanoacrylate

There total 3 articles about 2-Methoxyethyl 2-cyanoacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

→ 2-methoxyethyl 2-cyanoacrylate (27816-23-5)

Guidance literature:

With piperazine; dodecylbenzene-sulphonic acid; at 120 - 130 ℃; for 2h;

Reference yield: 52.0%

Dimethoxymethane (109-87-5) + 2-methoxyethyl cyanoacetate (10258-54-5) → 2-methoxyethyl 2-cyanoacrylate (27816-23-5)

Guidance literature:

With piperdinium acetate; at 130 ℃; for 6h;

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 2-methoxyethyl cyanoacetate (10258-54-5) → 2-methoxyethyl 2-cyanoacrylate (27816-23-5)

Guidance literature:

With methanol; sodium methylate; Erhitzen des Reaktionsprodukts mit Phosphor(V)-oxid, Schwefeldioxid und Hydrochinon unter vermindertem Druck auf 160-220gradC;

upstream raw materials:

formaldehyd

2-methoxyethyl cyanoacetate

Dimethoxymethane

Refernces

• 1、 -. "Process for preparing 1,1-disubstituted ethylenic monomers". Paragraph 0092; 0106. . Retrieved 2015/11/16.