1-Phenyl-2-propanone ethylene acetal

Base Information

• Chemical Name: 1-Phenyl-2-propanone ethylene acetal
• CAS No.: 4362-18-9
• Molecular Formula: C11H14O2
• Molecular Weight: 178.231
• Hs Code.: 2932999099
• Mol file: 4362-18-9.mol

Synonyms:2-benzyl-2-methyl-[1,3]dioxolane;1,2-benzyl-2-methyl;1,3-Dioxolane,2-benzyl-2-methyl;1,2-methyl-2-(phenylmethyl);2-Benzyl-2-methyl-[1,3]dioxolan;

Chemical Property of 1-Phenyl-2-propanone ethylene acetal

Chemical Property:

• Vapor Pressure: 0.00996mmHg at 25°C
• Boiling Point: 248.1°Cat760mmHg
• Flash Point: 105.9°C
• PSA: 18.46000
• Density: 1.063g/cm³
• LogP: 1.99210

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Phenyl-2-propanone ethylene acetal

There total 7 articles about 1-Phenyl-2-propanone ethylene acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

2-(1-iodo-2-phenylpropan-2-yloxy)ethanol → 2-benzyl-2-methyl-1,3-dioxolane (4362-18-9)

Guidance literature:

With Oxone; In ethylene glycol; at 20 ℃; for 2h;

DOI:10.1039/c5ra11092k

Reference yield: 40.0%

allylbenzene (300-57-2,57807-91-7) + ethylene glycol (107-21-1) → 2-benzyl-2-methyl-1,3-dioxolane (4362-18-9) + 1-phenyl-acetone (103-79-7,136675-26-8)

Guidance literature:

With oxygen; copper(l) chloride; palladium dichloride; In 1,2-dimethoxyethane;

DOI:10.1039/c39830000848

Reference yield: 14.0%

allylbenzene (300-57-2,57807-91-7) → 2-benzyl-2-methyl-1,3-dioxolane (4362-18-9) + 1-phenyl-acetone (103-79-7,136675-26-8)

Guidance literature:

With oxygen; ethylene glycol; copper(l) chloride; palladium dichloride; In 1,2-dimethoxyethane;

DOI:10.1039/c39830000848

upstream raw materials:

1,3-dioxolane-2-spirocyclohexane

2-(4-nitrophenyl)-2-methyl-1,3-dioxolane

1-phenyl-acetone

allylbenzene

Downstream raw materials:

(2-iodopropyl)benzene

1-phenyl-acetone

2-methyl-1,3-dioxacyclopentane radical cation

benzyl radical

Refernces

• 1、 Santos, Laura L.,Ruiz, Violeta R.,Sabater, Maria J.,Corma, Avelino. "Regioselective transformation of alkynes into cyclic acetals and thioacetals with a gold(I) catalyst: comparison with Br?nsted acid catalysts". . p. 7902 - 7909. Retrieved 2008/12/21.
• 2、 Hosokawa, Takahiro,Ohta, Toshiyuki,Murahashi, Shun-Ichi. "Palladium(II)-catalysed Acetalization of Terminal Olefins Bearing Electron-withdrawing Substituents with 1,3- and 1,2-Diols". . p. 848 - 849. Retrieved 2007/10/02.