9-Methoxybicyclo[4.2.1]nona-2,4-diene

Base Information

• Chemical Name: 9-Methoxybicyclo[4.2.1]nona-2,4-diene
• CAS No.: 64725-62-8
• Molecular Formula: C₁₀H₁₄O
• Molecular Weight: 150.221
• DSSTox Substance ID: DTXSID00983364
• Mol file: 64725-62-8.mol

Synonyms:64725-62-8;9-methoxybicyclo[4.2.1]nona-2,4-diene;Bicyclo[4.2.1]nona-2,4-diene,9-methoxy-syn-;Bicyclo(4.2.1)nona-2,4-diene, 9-methoxy-, syn-;DTXSID00983364

Chemical Property of 9-Methoxybicyclo[4.2.1]nona-2,4-diene

Chemical Property:

• Vapor Pressure: 0.313mmHg at 25°C
• Boiling Point: 208.1°Cat760mmHg
• Flash Point: 72°C
• PSA: 9.23000
• Density: 0.99g/cm³
• LogP: 2.15360
• XLogP3: 2.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 150.104465066
• Heavy Atom Count: 11
• Complexity: 173

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1C2CCC1C=CC=C2

Technology Process of 9-Methoxybicyclo[4.2.1]nona-2,4-diene

There total 2 articles about 9-Methoxybicyclo[4.2.1]nona-2,4-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1S,6R)-Bicyclo[4.2.1]nona-2,4-dien-9-one → syn-9-Methoxybicyclo<4,2,1>nona-2,4-dien (64725-62-8)

Guidance literature:

Multi-step reaction with 2 steps

1: NaBH₄

2: NaH

With sodium tetrahydroborate; sodium hydride;

DOI:10.1021/ja00462a006

Reference yield:

syn-9-Bicyclo<4,2,1>nona-2,4-dien-9-ol (64725-60-6,64725-61-7) + methyl iodide (74-88-4) → syn-9-Methoxybicyclo<4,2,1>nona-2,4-dien (64725-62-8)

Guidance literature:

With sodium hydride;

DOI:10.1021/ja00462a006

upstream raw materials:

syn-9-Bicyclo<4,2,1>nona-2,4-dien-9-ol

methyl iodide