bis(2,4,6-trinitrophenyl) sulphide

Base Information

• Chemical Name: bis(2,4,6-trinitrophenyl) sulphide
• CAS No.: 2217-06-3
• Molecular Formula: C12H4 N6 O12 S
• Molecular Weight: 456.263
• Hs Code.: 2930909090
• Mol file: 2217-06-3.mol

Synonyms:Picrylsulfide (6CI,7CI,8CI); 2,2',4,4',6,6'-Hexanitrodiphenyl sulfide;2,4,6,2',4',6'-Hexanitrodiphenyl sulfide; 2,4,6-Trinitrophenyl sulfide;Bis(2,4,6-trinitrophenyl) sulfide; Dipicryl sulfide; NSC 243670

Chemical Property of bis(2,4,6-trinitrophenyl) sulphide

Chemical Property:

• Vapor Pressure: 7.8E-11mmHg at 25°C
• Melting Point: 226 °C(Solv: ethyl acetate (141-78-6); ethanol (64-17-5))
• Refractive Index: 1.7000 (estimate)
• Boiling Point: 531.3°Cat760mmHg
• Flash Point: 275.1°C
• PSA: 300.22000
• Density: 1.96g/cm³
• LogP: 6.42620

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis(2,4,6-trinitrophenyl) sulphide

There total 16 articles about bis(2,4,6-trinitrophenyl) sulphide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

2,4,6-trinitrochlorobenzene (88-88-0) → dipicryl sulfide (2217-06-3)

Guidance literature:

With sodium thiosulfate; magnesium carbonate; In ethanol; for 1h; Reflux;

DOI:10.1021/jacs.9b11086

Reference yield:

2,4,6-trinitrochlorobenzene (88-88-0) + thiourea (17356-08-0) → dipicryl sulfide (2217-06-3)

Guidance literature:

With ethanol; calcium carbonate;

Reference yield:

1-picryl-pyridinium; chloride (6509-51-9) → dipicryl sulfide (2217-06-3)

Guidance literature:

With hydrogen sulfide; water;

upstream raw materials:

2,4,6-trinitrochlorobenzene

1,1-diphenylthiourea

1-picryl-pyridinium; chloride

acetic acid

Downstream raw materials:

bis(2,4,6-trinitrophenyl) sulfone

2,4,6-Trinitrophenol

2,4,6-trinitro-phenetole

ammonia

Refernces

• 1、 Nurgatin, V. V.,Ginzburg, B. M.,Egorova, L. S.,Beskrovnaya, T. G.. "INVESTIGATION IN THE SERIES OF 2,4,6-TRINITROTHIOPHENOL DERIVATIVES. EFFECT OF DIPOLAR APROTIC SOLVENTS ON THE REACTIVITY OF 2,4,6-TRINITROTHIOPHENOL POTASSIUM SALT IN REACTION WITH 1-CHLORO-2,4,6-TRINITROBENZENE". . p. 495 - 498. Retrieved 2007/10/02.