Methyltriphenylarsonium iodide

Base Information

• Chemical Name: Methyltriphenylarsonium iodide
• CAS No.: 1499-33-8
• Molecular Formula: C19H18 As . I
• Molecular Weight: 448.178
• Hs Code.: 2931900090
• European Community (EC) Number: 216-108-8
• NSC Number: 47642
• DSSTox Substance ID: DTXSID70883685
• Mol file: 1499-33-8.mol

Synonyms:Methyltriphenylarsonium iodide;1499-33-8;Arsonium, methyltriphenyl-, iodide (1:1);methyl(triphenyl)arsanium;iodide;Arsonium, methyltriphenyl-, iodide;EINECS 216-108-8;NSC 47642;Triphenylmethylarsonium iodide;C19H18As.I;Methyl triphenylarsonium iodide;Triphenylmethylarsoniumiodide;SCHEMBL5091418;C19-H18-As.I;DTXSID70883685;METHYLTRIPHENYLARSONIUMIODIDE;BAA49933;NSC47642;MFCD00031543;NSC-47642;AKOS002378406;CS-0447065;FT-0628925;M0327;D91317

Chemical Property of Methyltriphenylarsonium iodide

Chemical Property:

• Appearance/Colour: light yellow crystalline powder
• Melting Point: 171-175 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -0.20940
• Sensitive.: Light Sensitive
• Solubility.: soluble in Methanol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 447.96692
• Heavy Atom Count: 21
• Complexity: 235

Purity/Quality:

99% ^*data from raw suppliers

Methyltriphenylarsonium Iodide >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 23/25
• Safety Statements: 45-28A-20/21

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[As+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[I-]

Technology Process of Methyltriphenylarsonium iodide

There total 9 articles about Methyltriphenylarsonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

methyltriphenylarsonium triiodide → triphenylmethylarsonium iodide (1499-33-8)

Guidance literature:

With tert-butylamine; In acetone; Heating;

Reference yield:

triphenyl-arsane (603-32-7) + methyl iodide (74-88-4) → triphenylmethylarsonium iodide (1499-33-8)

Guidance literature:

Reference yield:

diphenylmethylarsine (945-48-2) → triphenylmethylarsonium iodide (1499-33-8)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium permanganate; acetone

2: benzene; diethyl ether

With potassium permanganate; diethyl ether; acetone; benzene;

DOI:10.1021/ja01269a053

upstream raw materials:

diphenylmethylarsine oxide

phenylmagnesium iodide

triphenyl-arsane

methyl iodide

Downstream raw materials:

(E)-3-Pentafluorophenyl-1-piperidin-1-yl-propenone

(E)-3-(4-Chloro-2,3,5,6-tetrafluoro-phenyl)-1-piperidin-1-yl-propenone

(E)-N,N-Diethyl-3-pentafluorophenyl-acrylamide

(E)-N,N-Diisopropyl-3-pentafluorophenyl-acrylamide