4-Chlorobenzaldehyde oxime

Base Information

• Chemical Name: 4-Chlorobenzaldehyde oxime
• CAS No.: 3848-36-0
• Molecular Formula: C7H6ClNO
• Molecular Weight: 155.584
• Hs Code.: 2928000090
• European Community (EC) Number: 636-813-8
• NSC Number: 68354,65231,74
• Nikkaji Number: J119.239F
• Wikidata: Q82227883
• ChEMBL ID: CHEMBL135560
• Mol file: 3848-36-0.mol

Synonyms:4-Chlorobenzaldehyde oxime;3848-36-0;4-chlorobenzenecarbaldehyde oxime;p-Chlorobenzaldoxime;p-Chlorobenzaldehyde oxime;(NE)-N-[(4-chlorophenyl)methylidene]hydroxylamine;3717-24-6;Benzaldehyde, p-chloro-, oxime;4-Chlorobenzaldoxime;MFCD00016412;(E)-4-Chlorobenzaldehyde oxime;Benzaldehyde, 4-chloro-, oxime;p-Chloro-syn-benzaldoxime;Benzaldehyde, p-chloro-, oxime, (E)-;Benzaldehyde, 4-chloro-, oxime, (E)-;4-Chlorbenzaldoxime;4-Chlorobenzaloxime;syn-p-Chlorobenzaldoxime;(E)-N-[(4-chlorophenyl)methylidene]hydroxylamine;N-[(4-chlorophenyl)methylidene]hydroxylamine;(E)-4-Chlorobenzaldoxime;(E)-1-(4-chlorophenyl)-N-hydroxymethanimine;e-p-chlorobenzaldehyde oxime;NSC74;(E)-4-Chlorobenzaldehydeoxime;CHEMBL135560;NSC-74;SCHEMBL1505539;(Z)-4-Chlorobenzaldehyde oxime;(Z)-4-Chloro-benzaldehyde oxime;QKWBTCRVPQHOMT-WEVVVXLNSA-N;HMS1752C18;NSC65231;NSC68354;NSC-65231;NSC-68354;STK887675;AKOS000304360;CS-W016247;NCGC00343097-01;10L-355S;EN300-15681;AB00626803-03;A824171;J-501979;Z49568332

Chemical Property of 4-Chlorobenzaldehyde oxime

Chemical Property:

• Vapor Pressure: 0.0314mmHg at 25°C
• Melting Point: 108-110 °C
• Refractive Index: 1.55
• Boiling Point: 233.2 °C at 760 mmHg
• PKA: 10.45±0.10(Predicted)
• Flash Point: 94.8 °C
• PSA: 32.59000
• Density: 1.217 g/cm³
• LogP: 2.14810
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 155.0137915
• Heavy Atom Count: 10
• Complexity: 119

Purity/Quality:

99% ^*data from raw suppliers

4-ChlorobenzaldehydeOxime ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC(=CC=C1C=NO)Cl
• Isomeric SMILES: C1=CC(=CC=C1/C=N/O)Cl

Technology Process of 4-Chlorobenzaldehyde oxime

There total 27 articles about 4-Chlorobenzaldehyde oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-chlorobenzaldehyde (104-88-1) → 4-chlorobenzaldoxime (3848-36-0)

Guidance literature:

With hydroxylamine hydrochloride; sodium carbonate; In ethanol; at 20 ℃;

DOI:10.1039/c2ob26699g

Reference yield: 95.0%

2-(4-chlorobenzyloxy)tetrahydro-2H-pyran (18484-03-2) → 4-chlorobenzaldoxime (3848-36-0)

Guidance literature:

With trichloroisocyanuric acid; hydroxylamine hydrochloride; In neat (no solvent); at 110 ℃; for 1h; Green chemistry;

DOI:10.1080/10426507.2014.990015

Reference yield: 94.0%

para-Chlorobenzyl alcohol (873-76-7) → 4-chlorobenzaldoxime (3848-36-0)

Guidance literature:

With hydroxylamine hydrochloride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; at 100 ℃; for 12h; chemoselective reaction; Neat (no solvent);

DOI:10.5012/bkcs.2012.33.4.1209

upstream raw materials:

piperidine

4-Chloro-benzaldehyde O-(2,4-dinitro-phenyl)-oxime

2-(4-chlorophenyl)-1,3-dioxolane

dibenzylcarbamyl chloride

Downstream raw materials:

p-Chlor-benzaldehydoxim-diethylorthoacetat

O--p-chlor-benzaldoxim

4-(4-chlorophenyl)-2,7-dioxa-3-azabicyclo<3,3,0>oct-3-ene

4-Cyanochlorobenzene