cis-3-Tridecene

Base Information

• Chemical Name: cis-3-Tridecene
• CAS No.: 41446-53-1
• Molecular Formula: C13H26
• Molecular Weight: 182.349
• UNII: 7RY0E2S0NR
• DSSTox Substance ID: DTXSID40880767
• Nikkaji Number: J364.002G
• Wikidata: Q27268770
• Mol file: 41446-53-1.mol

Synonyms:cis-3-Tridecene;3-Tridecene, (Z)-;3-Tridecene, (Z);3-Tridecene, (3Z)-;(Z)-3-Tridecene;(3Z)-3-Tridecene;UNII-7RY0E2S0NR;7RY0E2S0NR;41446-53-1;.GAMMA.-CIS-TRIDECENE;DTXSID40880767;OMBXNSHDJUALCV-ALCCZGGFSA-N;Q27268770

Chemical Property of cis-3-Tridecene

Chemical Property:

• Vapor Pressure: 0.0903mmHg at 25°C
• Boiling Point: 232.3°Cat760mmHg
• Flash Point: 87.2°C
• PSA: 0.00000
• Density: 0.77g/cm³
• LogP: 5.09330
• XLogP3: 6.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 182.203450829
• Heavy Atom Count: 13
• Complexity: 103

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCC=CCC
• Isomeric SMILES: CCCCCCCCC/C=C\CC

Technology Process of cis-3-Tridecene

There total 3 articles about cis-3-Tridecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lead(IV) tetraacetate (546-67-8) + n-tetradecanoic acid (544-63-8) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → (+/-)-2-Tridecanyl acetate (41015-28-5,136376-56-2) + 3-acetoxytridecane (60826-31-5) + Tridecane (629-50-5) + 1-tridecene (2437-56-1) + n-tridecyl acetate (1072-33-9) + cis-tridec-6-ene (6508-77-6) + (E)-tridec-6-ene (6434-76-0) + (Z)-tridec-5-ene (25524-42-9) + trans-5-tridecene (23051-84-5) + (Z)-tridec-4-ene (41446-54-2) + trans-4-tridecene (41446-55-3) + cis-3-tridecene (41446-53-1) + trans-3-tridecene (41446-57-5) + (Z)-tridec-2-ene (41446-59-7) + (E)-tridec-2-ene (41446-58-6) + tridecylbenzene (123-02-4) + 6-acetoxytridecane (60826-27-9) + 5-acetoxytridecane (60826-29-1) + 4-acetoxytridecane (60826-30-4)

Guidance literature:

at 81 ℃;

DOI:10.1016/j.molstruc.2013.02.020

Reference yield:

caprinaldehyde (112-31-2) + n-propyltriphenylphosphonium bromide (6228-47-3) → cis-3-tridecene (41446-53-1) + trans-3-tridecene (41446-57-5)

Guidance literature:

With potassium carbonate; In 1,4-dioxane; water; for 3.5h; Yield given. Yields of byproduct given; Heating;

Reference yield:

→ cis-3-tridecene (41446-53-1)

Guidance literature:

Durch stufenweise Alkylierung v. Acetylen u. anschl. Hydrierung;

upstream raw materials:

caprinaldehyde

n-propyltriphenylphosphonium bromide

lead(IV) tetraacetate

n-tetradecanoic acid