cis-2-Tridecene

Base Information

• Chemical Name: cis-2-Tridecene
• CAS No.: 41446-59-7
• Molecular Formula: C13H26
• Molecular Weight: 182.349
• UNII: DA9736F843
• DSSTox Substance ID: DTXSID00880864
• Nikkaji Number: J364.000K
• Wikidata: Q27276306
• Mol file: 41446-59-7.mol

Synonyms:cis-2-Tridecene;2-Tridecene, (Z)-;(2Z)-2-Tridecene;2-Tridecene, (Z);2-Tridecene, (2Z)-;41446-59-7;DA9736F843;(z)-2-tridecene;UNII-DA9736F843;Z-2-TRIDECENE;.BETA.-CIS-TRIDECENE;DTXSID00880864;Q27276306

Chemical Property of cis-2-Tridecene

Chemical Property:

• Vapor Pressure: 0.0771mmHg at 25°C
• Boiling Point: 235.3°Cat760mmHg
• Flash Point: 88°C
• PSA: 0.00000
• Density: 0.77g/cm³
• LogP: 5.09330
• XLogP3: 7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 182.203450829
• Heavy Atom Count: 13
• Complexity: 103

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCC=CC
• Isomeric SMILES: CCCCCCCCCC/C=C\C

Technology Process of cis-2-Tridecene

There total 3 articles about cis-2-Tridecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

Decyl-oxiran (2855-19-8) + methyllithium (917-54-4) → tridecan-3-ol (10289-68-6) + (Z)-tridec-2-ene (41446-59-7) + (E)-tridec-2-ene (41446-58-6)

Guidance literature:

With 2,2,6,6-tetramethylpiperidinyl-lithium; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 2h; Further Variations:; Solvents; Reagents; Product distribution;

DOI:10.1021/jo070291v

Reference yield:

lead(IV) tetraacetate (546-67-8) + n-tetradecanoic acid (544-63-8) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → (+/-)-2-Tridecanyl acetate (41015-28-5,136376-56-2) + 3-acetoxytridecane (60826-31-5) + Tridecane (629-50-5) + 1-tridecene (2437-56-1) + n-tridecyl acetate (1072-33-9) + cis-tridec-6-ene (6508-77-6) + (E)-tridec-6-ene (6434-76-0) + (Z)-tridec-5-ene (25524-42-9) + trans-5-tridecene (23051-84-5) + (Z)-tridec-4-ene (41446-54-2) + trans-4-tridecene (41446-55-3) + cis-3-tridecene (41446-53-1) + trans-3-tridecene (41446-57-5) + (Z)-tridec-2-ene (41446-59-7) + (E)-tridec-2-ene (41446-58-6) + tridecylbenzene (123-02-4) + 6-acetoxytridecane (60826-27-9) + 5-acetoxytridecane (60826-29-1) + 4-acetoxytridecane (60826-30-4)

Guidance literature:

at 81 ℃;

DOI:10.1016/j.molstruc.2013.02.020

Reference yield:

Tridecane (629-50-5) → 1-tridecene (2437-56-1) + (Z)-tridec-2-ene (41446-59-7) + (E)-tridec-2-ene (41446-58-6)

Guidance literature:

at 24.9 ℃; under 760 Torr; Thermodynamic data; ΔH⁰, ΔS⁰; thermodynamic parameters of dehydration reaction of normal paraffins to olefins; entalpy end entropy differences for the formation of monoolefins from normal paraffins;

DOI:10.1007/BF00962295

upstream raw materials:

Tridecane

Decyl-oxiran

methyllithium

lead(IV) tetraacetate

Downstream raw materials:

tridecan-3-ol

tridecan-2-ol

Tridecane

tridecan-1-ol