Tricyclohexyltin bromide

Base Information

• Chemical Name: Tricyclohexyltin bromide
• CAS No.: 3023-92-5
• Molecular Formula: C18H33BrSn
• Molecular Weight: 448.074
• Hs Code.: 2931900090
• NSC Number: 99049
• UNII: CN14V4XG9P
• DSSTox Substance ID: DTXSID30184327
• Mol file: 3023-92-5.mol

Synonyms:tricyclohexyltin bromide;3023-92-5;bromo(tricyclohexyl)stannane;Bromotricyclohexylstannane;Stannane, bromotricyclohexyl-;CN14V4XG9P;NSC 99049;NSC-99049;NSC99049;C18H33BrSn;UNII-CN14V4XG9P;C18-H33-Br-Sn;SCHEMBL8979634;TIN, BROMOTRICYCLOHEXYL-;DTXSID30184327;FT-0634608

Chemical Property of Tricyclohexyltin bromide

Chemical Property:

• Vapor Pressure: 6.91E-07mmHg at 25°C
• Melting Point: 77 °C
• Boiling Point: 420.4 °C at 760 mmHg
• Flash Point: 208 °C
• PSA: 0.00000
• LogP: 7.32970
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 448.07877
• Heavy Atom Count: 20
• Complexity: 240

Purity/Quality:

99% ^*data from raw suppliers

TRICYCLOHEXYLTIN BROMIDE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(CC1)[Sn](C2CCCCC2)(C3CCCCC3)Br

Technology Process of Tricyclohexyltin bromide

There total 11 articles about Tricyclohexyltin bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclohexylmagnesium bromide (931-50-0) → tris(cyclohexyl)tin bromide (3023-92-5)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether

In diethyl ether;

Reference yield:

tricyclohexyl(iodomethyl)stannane (130876-82-3) → tris(cyclohexyl)tin bromide (3023-92-5)

Guidance literature:

Multi-step reaction with 2 steps

1: ethanol

2: Br₂ / tetrachloromethane

With Br₂; In tetrachloromethane; ethanol;

DOI:10.1016/S0020-1693(00)80860-9

Reference yield:

{(p-chloro-phenylthio)methyl}tricyclohexylstannane (130876-78-7) → (bromomethyl)(4-chlorophenyl)sulfane (83767-73-1) + tris(cyclohexyl)tin bromide (3023-92-5)

Guidance literature:

With Br₂; In tetrachloromethane; 4 days, room temp.; monitored by (1)H-NMR;

DOI:10.1016/S0020-1693(00)80860-9

upstream raw materials:

bromine

Tetracyclohexyl-stannan

iodine(I) bromide

hydrogen bromide

Downstream raw materials:

Tetracyclohexyl-stannan

hexacyclohexylditin

(CH₃)3SnSn(C₆H₁₁)3

(C₄H₉)3SnSn(C₆H₁₁)3

Refernces

• 1、 Singhal, Kiran. "Electrophilic cleavage of tin-alicyclic and tin-aryl bonds involving the synthesis of cyclohexyl-tin, -tellurium and -antimony compounds - Part I". . p. 542 - 544. Retrieved 2007/10/02.