CYCLOHEXYLMAGNESIUM BROMIDE

Base Information

• Chemical Name: CYCLOHEXYLMAGNESIUM BROMIDE
• CAS No.: 931-50-0
• Molecular Formula: C6H11 Br Mg
• Molecular Weight: 187.362
• Hs Code.: 29319090
• Mol file: 931-50-0.mol

Synonyms:Cyclohexylmagnesiumbromide (6CI); Bromo(cyclohexyl)magnesium

Chemical Property of CYCLOHEXYLMAGNESIUM BROMIDE

Chemical Property:

• Flash Point: -17°C (THF)
• PSA: 0.00000
• LogP: 3.13390

Purity/Quality:

98%,99%, ^*data from raw suppliers

CyclohexylmagnesiumBromide(~1.0MinTHF) ^*data from reagent suppliers

Safty Information:

• Statements: 11-19-36/37/38-36/37-14
• Safety Statements: 16-29-33

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CYCLOHEXYLMAGNESIUM BROMIDE

There total 3 articles about CYCLOHEXYLMAGNESIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-bromocyclohexane (108-85-0) + magnesium (7439-95-4) → cyclohexylmagnesium bromide (931-50-0)

Guidance literature:

With lithium chloride; In tetrahydrofuran; at 0 - 25 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

DOI:10.1055/s-0036-1589101

Reference yield:

1-bromocyclohexane (108-85-0) → cyclohexylmagnesium bromide (931-50-0)

Guidance literature:

With magnesium; In diethyl ether;

Reference yield:

1-bromocyclohexane (108-85-0) + diethyl ether (60-29-7,927820-24-4) → cyclohexylmagnesium bromide (931-50-0)

Guidance literature:

upstream raw materials:

1-bromocyclohexane

diethyl ether

magnesium

Downstream raw materials:

cyclohexylethan-1-ol

2-cyclohexyltetrahydropyran

2-Cyclohexyl-2-(2-thienyl)glykolsaeure

1-cyclohexylisochroman

Refernces

• 1、 Li, Jie,Ren, Qianyi,Cheng, Xinyi,Karaghiosoff, Konstantin,Knochel, Paul. "Chromium(II)-Catalyzed Diastereoselective and Chemoselective Csp2-Csp3 Cross-Couplings Using Organomagnesium Reagents". supporting information. p. 18127 - 18135. Retrieved 2019/11/19.
• 2、 Benischke, Andreas D.,Desaintjean, Alexandre,Juli, Thomas,Cahiez, Gérard,Knochel, Paul. "Nickel-Catalyzed Cross-Coupling of Functionalized Organo manganese Reagents with Aryl and Heteroaryl Halides Promoted by 4-Fluorostyrene". supporting information. p. 5396 - 5412. Retrieved 2017/12/14.