Technology Process of Dimethyltin(2)
There total 2 articles about Dimethyltin(2) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
fluorosulphonic acid;
In
fluorosulphonic acid;
byproducts: H2, Sn(2+), H2SO4; solvolysis in HSO3F at low temp., warming to room temp.;; react. was monitored by NMR and Moessbauer spectroscopy; further by-products: SO2, HF, SO3F(1-);;
- Guidance literature:
-
With
fluorosulphonic acid;
In
fluorosulphonic acid;
byproducts: H2; solvolysis in HSO3F at low temp.;; react. was monitored by NMR;;
- Guidance literature:
-
With
NaClO4;
In
water;
mixing in metal-to-ligand ratio of Me2Sn(IV)(2+):captopril=1:1 or 1:10 in the neutral and weakly basic pH range at 298 K (I=0.1 mol dm**-3 NaClO4); monitoring by NMR, MAS and MOE;
DOI:10.1016/S0022-328X(03)00015-9