2067-76-7Relevant academic research and scientific papers
Vacuum ultraviolet and photoelectron spectra of dimethyl- and trimethyl-stannane
Lespes, G.,Dargelos, A.,Fernandez-Sanz, J.
, p. 41 - 50 (1989)
The vacuum ultraviolet spectra of dimethyl- and trimethyl-stannane between 220 and 110 nm are reported.Comparison of the spectroscopic data (photoelectron and vacuum UV) for compounds of general formula SnHn(CH3)4-n have been used to reveal the effects of methylation on the stability of radical ions and the first Rydberg states.A comparison with results for the corresponding alkane, silane and germane series reveals a progressive increase in the energy of the valence electrons as the atomic number of the central atom increases.
New and efficient synthesis of solid-supported organotin reagents and their use in organic synthesis
Hernán, Alejandro G.,Horton, Peter N.,Hursthouse, Michael B.,Kilburn, Jeremy D.
, p. 1466 - 1475 (2007/10/03)
Novel resin-bound organotin reagents have been prepared, including for the first time resin-bound dimethyl tin reagents. Mild methodology has also been developed for the very efficient synthesis of resin-bound distannanes. The resin-bound tin chloride rea
SOME OBSERVATIONS ON PENTACARBONYLMANGANESE-SUBSTITUTED TIN HYDRIDES
Foster, Stephen P.,Mackay, Kenneth M.
, p. 21 - 26 (2007/10/02)
The substituted tin hydrides, (CO)5MnSnH3, (CO)5MnSnMeH2, and (CO)5MnSnMe2H, have been synthesised and characterised with reasonable certainty by IR, MS and 1H NMR spectroscopy, despite some difficulties with decomposition. (CO)5MnSnH3 is the least stable
