2 3 7 8 12 13 17 18-OCTAETHYL-21H 23H-

Base Information

• Chemical Name: 2 3 7 8 12 13 17 18-OCTAETHYL-21H 23H-
• CAS No.: 24804-00-0
• Molecular Formula: C36H44N4Pd
• Molecular Weight: 639.1814
• Mol file: 24804-00-0.mol

Synonyms:21H,23H-Porphine, 2,3,7,8,12,13,17,18-octaethyl-, palladium complex;(2,3,7,8,12,13,17,18-Octaethylporphyrinato)palladium;(Octaethylporphyrinato)palladium;Octaethylporphinatopalladium;Palladiumoctaethylporphyrin;Palladium(2+) octaethylporphyrin;Palladium(II)octaethylporphyrin;Palladium-octaethylporphine;PdOEP;Palladium, [2,3,7,8,12,13,17,18-octaethylporphinato(2-)]- (8CI);Palladium,[2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-4-1)-;

Chemical Property of 2 3 7 8 12 13 17 18-OCTAETHYL-21H 23H-

Chemical Property:

• PSA: 34.58000
• LogP: 6.13420

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine palladium(II) Dye content 85 % ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2 3 7 8 12 13 17 18-OCTAETHYL-21H 23H-

There total 4 articles about 2 3 7 8 12 13 17 18-OCTAETHYL-21H 23H- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

2,3,7,8,12,13,17,18-octaethylporphyrin (106117-28-6,991-75-3) + palladium dichloride → 2,3,7,8,12,13,17,18-octaethylporphyrinatopalladium(II) (24804-00-0)

Guidance literature:

In further solvent(s); dissolving of 2,3,7,8,12,13,17,18-octaethylporphine and PdCl2 in molar ratio of 1:10 in DMF; reflux for 2 min; cooling, pptn., filtration, pouring into H2O; pptn., filtation, washing with H2O, chromy. on silica gel (CHCl3:C6H12 (1:2) as eluent); elem. anal.;

DOI:10.1134/S0036023607020180

Reference yield:

C38H47N5Pd → 2,3,7,8,12,13,17,18-octaethylporphyrinatopalladium(II) (24804-00-0) + C37H43N5Pd

Guidance literature:

With potassium tert-butylate; In N,N-dimethyl-formamide; Inert atmosphere;

DOI:10.1002/ejoc.201801659

Reference yield:

C44H51N5Pd → 2,3,7,8,12,13,17,18-octaethylporphyrinatopalladium(II) (24804-00-0) + C37H43N5Pd

Guidance literature:

With potassium tert-butylate; In N,N-dimethyl-formamide; Inert atmosphere;

DOI:10.1002/ejoc.201801659

upstream raw materials:

2,3,7,8,12,13,17,18-octaethylporphyrin

palladium diacetate

Refernces

• 1、 Lomova,Klyueva,Tyulyaeva, E. Yu.. "Structural modification and kinetic stability of octaethylporphyne complexes with palladium (II)". . p. 926 - 933. Retrieved 2011/08/04.
• 2、 Chizhova,Mamardashvili. "Effect of the chemical modification of the tetrapyrrole macrocycle on the reactivity of porphyrins in complexation with Pt4+ and Pd 2+ cations". . p. 250 - 253. Retrieved 2008/10/09.