Phosphorotrithioic acid, S,S,S-triphenyl ester

Base Information

• Chemical Name: Phosphorotrithioic acid, S,S,S-triphenyl ester
• CAS No.: 597-83-1
• Molecular Formula: C18H15OPS3
• Molecular Weight: 374.488
• DSSTox Substance ID: DTXSID70208410
• Nikkaji Number: J136.499E
• Wikidata: Q83082530
• Mol file: 597-83-1.mol

Synonyms:Triphenyl phosphorotrithioate;Phosphorotrithioic acid, S,S,S-triphenyl ester;597-83-1;C18H15OPS3;SCHEMBL1883203;S,S,S-triphenyl trithiophosphate;DTXSID70208410;C18-H15-O-P-S3;Trithiophosphoric acid S,S,S-triphenyl ester

Chemical Property of Phosphorotrithioic acid, S,S,S-triphenyl ester

Chemical Property:

• Vapor Pressure: 6.79E-11mmHg at 25°C
• Boiling Point: 532.8°Cat760mmHg
• Flash Point: 276°C
• Density: 1.34g/cm³
• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 374.00226562
• Heavy Atom Count: 23
• Complexity: 329

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)SP(=O)(SC2=CC=CC=C2)SC3=CC=CC=C3

Technology Process of Phosphorotrithioic acid, S,S,S-triphenyl ester

There total 17 articles about Phosphorotrithioic acid, S,S,S-triphenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

triphenyl thiophosphite (1095-04-1) + 4-methyl-3-[(1-oxohexadecyl)oxy]-2(3H)-thiazolethione (89861-47-2) → pentadecane (629-62-9) + Oxyde de tri(thiophenyl)phosphine (597-83-1) + Pentadecyl-phosphonodithioic acid S,S-diphenyl ester (110907-28-3) + thiophenol (108-98-5) + 4-methylthiazole-2-thiol (5685-06-3)

Guidance literature:

With water; In chlorobenzene; Product distribution; Ambient temperature; effect of amount of reactant, without solvent;

DOI:10.1016/S0040-4039(00)94261-8

Reference yield: 67.0%

triphenyl thiophosphite (1095-04-1) + 4-methyl-3-[(1-oxohexadecyl)oxy]-2(3H)-thiazolethione (89861-47-2) → pentadecane (629-62-9) + Oxyde de tri(thiophenyl)phosphine (597-83-1) + Pentadecyl-phosphonodithioic acid S,S-diphenyl ester (110907-28-3) + thiophenol (108-98-5)

Guidance literature:

With water; Ambient temperature;

DOI:10.1016/S0040-4039(00)94261-8

Reference yield: 56.0%

thiophenol (108-98-5) → Oxyde de tri(thiophenyl)phosphine (597-83-1)

Guidance literature:

With phosphorous; air; triethylamine; In acetonitrile; at 70 - 90 ℃; for 15h;

DOI:10.1007/s11176-005-0329-4

upstream raw materials:

triphenyl thiophosphite

sodium thiophenolate

thiophenol

tert.-butylhydroperoxide

Downstream raw materials:

phosphoric acid

thiophenol