(Z)-7-Dodecenal

Base Information

• Chemical Name: (Z)-7-Dodecenal
• CAS No.: 63851-40-1
• Molecular Formula: C₁₂H₂₂O
• Molecular Weight: 182.306
• Metabolomics Workbench ID: 3556
• Mol file: 63851-40-1.mol

Synonyms:(Z)-7-Dodecenal;(Z)-dodec-7-enal;7Z-Dodecenal;63851-40-1;7-Dodecenal, (Z)-;7-dodecenal, Z;HTUHYXDEKCWDCI-WAYWQWQTSA-N;LMFA06000162;A901993

Chemical Property of (Z)-7-Dodecenal

Chemical Property:

• Vapor Pressure: 0.0114mmHg at 25°C
• Boiling Point: 261.7°C at 760 mmHg
• Flash Point: 112.7°C
• Density: 0.837g/cm³
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 9
• Exact Mass: 182.167065321
• Heavy Atom Count: 13
• Complexity: 127

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC=CCCCCCC=O
• Isomeric SMILES: CCCC/C=C\CCCCCC=O

Technology Process of (Z)-7-Dodecenal

There total 5 articles about (Z)-7-Dodecenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.5%

(Z)-7-dodecenol (20056-92-2) → (Z)-7-dodecenal (63851-40-1)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane;

Reference yield:

tetrahydropyranyl ether of 7-dodecyn-1-ol (16695-32-2) → (Z)-7-dodecenal (63851-40-1)

Guidance literature:

Multi-step reaction with 3 steps

1: p-TsOH / methanol

2: 76 percent / H₂ / Lindlar catalyst / hexane

3: 51.5 percent / PCC / CH₂Cl₂

With hydrogen; toluene-4-sulfonic acid; pyridinium chlorochromate; Lindlar's catalyst; In methanol; hexane; dichloromethane;

Reference yield:

2-[(6-bromohexyl)oxy]tetrahydro-2H-pyran (53963-10-3) → (Z)-7-dodecenal (63851-40-1)

Guidance literature:

Multi-step reaction with 4 steps

1: 1) n-BuLi, 2) HMPA / 1) THF, -10 deg C, 2) 25 deg C

2: p-TsOH / methanol

3: 76 percent / H₂ / Lindlar catalyst / hexane

4: 51.5 percent / PCC / CH₂Cl₂

With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium; hydrogen; toluene-4-sulfonic acid; pyridinium chlorochromate; Lindlar's catalyst; In methanol; hexane; dichloromethane;

upstream raw materials:

(Z)-7-dodecenol

tetrahydropyranyl ether of 7-dodecyn-1-ol

2-[(6-bromohexyl)oxy]tetrahydro-2H-pyran

1-bromo-6-hexanol