BIS(DIMETHYLDITHIOCARBAMATO)IRON

Base Information

• Chemical Name: BIS(DIMETHYLDITHIOCARBAMATO)IRON
• CAS No.: 15339-38-5
• Molecular Formula: C₆H₁₂FeN₂S₄
• Molecular Weight: 296.286
• Mol file: 15339-38-5.mol

Synonyms:Iron,bis(dimethylcarbamodithioato-S,S')-; Iron, bis(dimethyldithiocarbamato)-(7CI,8CI); Bis(dimethyldithiocarbamato)iron; Carbamodithioic acid, dimethyl-,iron(2+) salt; Nokmat F75; Trifungol

Chemical Property of BIS(DIMETHYLDITHIOCARBAMATO)IRON

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of BIS(DIMETHYLDITHIOCARBAMATO)IRON

There total 6 articles about BIS(DIMETHYLDITHIOCARBAMATO)IRON which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

triiron dodecarbonyl (17685-52-8) + Thiram (137-26-8,93196-73-7) → Fe(η2-S2CNMe2)2 (52690-05-8,15339-38-5) + Fe(CO)2(η2-S2CNMe2)2 (36309-89-4,93221-07-9)

Guidance literature:

In toluene; Irradiation (UV/VIS); irradiation of mixt. of Fe3(CO)12 and tetramethylthiuram disulphide in toluene with visible light for 0.5 h; evapg. solvent in vac.; chromy. of residue on a silica gel column; elution with petroleum ether/CH2Cl2 (50:50) and with neat CH2Cl2;

DOI:10.1016/S0277-5387(00)87152-1

Reference yield: 66.0%

diiron nonacarbonyl (15321-51-4) + Thiram (137-26-8,93196-73-7) → Fe(η2-S2CNMe2)2 (52690-05-8,15339-38-5) + Fe(CO)2(η2-S2CNMe2)2 (36309-89-4,93221-07-9)

Guidance literature:

In toluene; Irradiation (UV/VIS); irradiation of mixt. of Fe2(CO)9 (0.41 mmol) and tetramethylthiuram disulphide (0.41 mmol) in toluene with visible light for 0.5 h; evapg. solvent in vac.; chromy. of residue on a silica gel column; elution with petroleum ether/CH2Cl2 (50:50) and with neat CH2Cl2;

DOI:10.1016/S0277-5387(00)87152-1

Reference yield: 60.0%

diiron nonacarbonyl (15321-51-4) + tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten → tris(N,N-dimethyldithiocarbamato)iron(III) (14484-64-1,21696-59-3) + Fe(η2-S2CNMe2)2 (52690-05-8,15339-38-5) + Fe(CO)2(η2-S2CNMe2)2 (36309-89-4,93221-07-9)

Guidance literature:

In toluene; Irradiation (UV/VIS); irradiation with visible light for 2 h under argon;; solvent removed in vacuo, chromd. (silica gel, elution with petroleum ether/CH2Cl2 1/1 gave (CO)2-complex, elution with CH2Cl2 gave Fe(dtc)2);

DOI:10.1016/S0020-1693(00)86021-1

upstream raw materials:

triiron dodecarbonyl

Thiram

Fe(CO)2(η2-S2CNMe2)2

diiron nonacarbonyl

Refernces

• 1、 Mathur, Pradeep,Thimmappa. "Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species". . p. 119 - 122. Retrieved 2008/10/08.