(Z)-4-Dodecenal

Base Information

Chemical Name:(Z)-4-Dodecenal
CAS No.:21944-98-9
Molecular Formula:C12H22O
Molecular Weight:182.306
Hs Code.:2912190090
European Community (EC) Number:687-779-6
UNII:IJA6BV46A7
DSSTox Substance ID:DTXSID30885185
Nikkaji Number:J1.520.586E
Wikidata:Q27280754
Mol file:21944-98-9.mol

Synonyms:(Z)-4-Dodecenal;4-Dodecenal, (4Z)-;(Z)-dodec-4-enal;Tangerinal;21944-98-9;IJA6BV46A7;UNII-IJA6BV46A7;Tangerinal 2;4-dodecenal, Z;cis-4-DODECENAL;DODEC-4-ENAL;(Z)-4-dodecen-1-al;4-DODECENAL, CIS-;SCHEMBL229645;4-DODECENAL, (Z)-;FEMA NO. 4036;DTXSID30885185;CHEBI:172439;MMCDSVCBSAMNPL-UHFFFAOYSA-N;(Z)-4-DODECENAL [FHFI];Q27280754

Suppliers and Price of (Z)-4-Dodecenal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 24 raw suppliers

Chemical Property of (Z)-4-Dodecenal

Chemical Property:

Appearance/Colour:Colourless liquid; Fruity, citrusy aroma
Vapor Pressure:0.0155mmHg at 25°C
Melting Point:2°C (estimate)
Refractive Index:1.444
Boiling Point:256.3 °C at 760 mmHg
Flash Point:109 °C
PSA：17.07000
Density:0.837 g/cm³
LogP:3.88220
XLogP3:4.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:9
Exact Mass:182.167065321
Heavy Atom Count:13
Complexity:127

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCCC=CCCC=O
Isomeric SMILES:CCCCCCC/C=C\CCC=O

Technology Process of (Z)-4-Dodecenal

There total 3 articles about (Z)-4-Dodecenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: tetrahydro-5-octyl-2-oxofuran-3-carboxaldehyde

: 57084-18-1,2305-05-7
gamma-dodecalactone

: 21944-98-9
(Z)-4-dodecenal

: 174155-48-7
(E)-4-dodecenal

Guidance literature:: With ethyl acetate; In tetrahydrofuran; at 470 ℃; for 2h; optical yield given as %de; Inert atmosphere;
DOI:10.1002/hlca.201000447

Reference yield:

: 57084-18-1,2305-05-7
gamma-dodecalactone

: 21944-98-9
(Z)-4-dodecenal

: 174155-48-7
(E)-4-dodecenal

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium methanolate / diethyl ether / 3 h / 15 - 20 °C / Inert atmosphere

1.2: 0.5 h / 20 °C / Inert atmosphere

2.1: ethyl acetate / tetrahydrofuran / 2 h / 470 °C / Inert atmosphere

With potassium methanolate; ethyl acetate; In tetrahydrofuran; diethyl ether;
DOI:10.1002/hlca.201000447