CYCLOPENTADIENYLIRON DICARBONYL DIMER, 99

Base Information

• Chemical Name: CYCLOPENTADIENYLIRON DICARBONYL DIMER, 99
• CAS No.: 12154-95-9
• Molecular Formula: C₁₄H₁₀Fe₂O₄
• Molecular Weight: 353.925
• Hs Code.: 29310099
• Mol file: 12154-95-9.mol

Synonyms:Dicyclopentadienyldiirontetracarbonyl (6CI); Iron, di-m-carbonyldicarbonyldi-p-cyclopentadienyldi-, (Fe-Fe) (8CI); Bis(cyclopentadienyldicarbonyliron);Bis(cyclopentadienyliron dicarbonyl); Bis(dicarbonyl(h5-cyclopentadienyl)iron);Bis(dicarbonyl-p-cyclopentadienyliron);Bis(p-cyclopentadienyldicarbonyliron);Bis(p-cyclopentadienylirondicarbonyl);Bis[dicarbonyl(p-cyclopentadienyl)iron(II)];Cyclopentadienyldicarbonyliron dimer; Cyclopentadienylirondicarbonyl dimer; Di-m-carbonylbis[carbonyl(h5-cyclopentadienyl)iron]; Di-m-carbonyldicarbonylbis[(1,2,3,4,5-h)-2,4-cyclopentadien-1-yl]diiron;Di-m-carbonyldicarbonyldi-p-cyclopentadienyldiiron;Dicarbonyl-p-cyclopentadienyliron dimer;Dicarbonylcyclopentadienyliron dimer; Dicyclopentadienyliron dicarbonyl dimer;Dicyclopentadienyltetracarbonyldiiron;Tetracarbonylbis(cyclopentadienyl)diiron; Tetracarbonylbis(h5-cyclopentadienyl)diiron

Chemical Property of CYCLOPENTADIENYLIRON DICARBONYL DIMER, 99

Chemical Property:

• Melting Point: 194°C (dec.)
• PSA: 74.60000
• LogP: 3.43280
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: It is readily soluble in moderate polar organic solvents such as chloroform and pyridine, but less soluble in carbon tetrachlori

Purity/Quality:

98%,99%, ^*data from raw suppliers

Cyclopentadienyliron Dicarbonyl Dimer ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-20/22
• Safety Statements: 22-36/37/39-36/37

MSDS Files:

Useful:

• Uses: Cyclopentadienyliron dicarbonyl dimer is a workhorse in organometallic chemistry because it is inexpensive and rugged. It is also used as a pharmaceutical intermediates and chemical research.

Technology Process of CYCLOPENTADIENYLIRON DICARBONYL DIMER, 99

There total 1 articles about CYCLOPENTADIENYLIRON DICARBONYL DIMER, 99 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

methylcyclopentadienyl manganese(I) tricarbonyl + (η5-C5H5)Fe(CO)2(PPh2) + sodium thioethylate (811-51-8) → [FeMn(μ-CO)(μ-PPh2)(CO)2(Cp)(C5H4Me)] (237423-26-6,238091-40-2) + C14H10Fe2O4, red (12154-95-9,33221-55-5,32757-46-3)

Guidance literature:

With THF; In tetrahydrofuran; Irradiation (UV/VIS); Ar-atmosphere; treatment of Fe-complex with thiolate, addn. to slight excess of Mn-complex (previously irradiated in THF), stirring for 1 h, irradiation for 1 h, stirring for 1 h; filtration over Al2O3, evapn. (vac.), chromy. (Al2O3, CH2Cl2/hexane=1:3v/v, last fraction), crystn. (layering CH2Cl2 soln. with pentane, -20°C); elem. anal.;

DOI:10.1016/S0022-328X(99)00106-0

upstream raw materials:

sodium thioethylate

Refernces