Trifluorooxovanadium

Base Information

• Chemical Name: Trifluorooxovanadium
• CAS No.: 13709-31-4
• Molecular Formula: F₃OV
• Molecular Weight: 123.936
• Hs Code.: 2826908090
• European Community (EC) Number: 237-250-7
• DSSTox Substance ID: DTXSID901045977
• Wikipedia: Vanadium(V)_oxytrifluoride,Vanadium trifluoride oxide
• Mol file: 13709-31-4.mol

Synonyms:vanadium oxytrifluoride;vanadium(V) oxytrifluoride;VOF3 cpd

Chemical Property of Trifluorooxovanadium

Chemical Property:

• Appearance/Colour: yellow powder
• Melting Point: 300 °C
• Boiling Point: 480 °C
• PSA: 17.07000
• Density: 2.45
• LogP: 1.14180
• Sensitive.: Moisture Sensitive
• Solubility.: H2O: insoluble(lit.)
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 126.957557
• Heavy Atom Count: 5
• Complexity: 6.9

Purity/Quality:

97% ^*data from raw suppliers

VanadiumOxytrifluoride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C,Xi
• Hazard Codes: C,Xi
• Statements: 20/21/22-32-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: O=[V].F.F.F

Technology Process of Trifluorooxovanadium

There total 4 articles about Trifluorooxovanadium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

vanadium(V) oxychloride (7727-18-6) + sodium fluoride (7681-49-4) → vanadium(V) oxytrifluoride (13709-31-4,20888-71-5)

Guidance literature:

In neat (no solvent); byproducts: NaCl; on-line process; gaseous VOCl3 passed over solid NaF heated to 375°C; gaseous NaCl and VOF3 obtained; detd. by IR spectroscopy;

DOI:10.1016/S1386-1425(00)00305-X

Reference yield:

chlorine trifluoride (7790-91-2) + vanadium(V) oxychloride (7727-18-6) → vanadium(V) oxytrifluoride (13709-31-4,20888-71-5)

Guidance literature:

In not given; at ambiente temp.;;

Reference yield:

bromine trifluoride (7787-71-5) + vanadium(V) oxychloride (7727-18-6) → vanadium(V) oxytrifluoride (13709-31-4,20888-71-5)

Guidance literature:

In neat (no solvent);

DOI:10.1039/JR9490002979

upstream raw materials:

chlorine trifluoride

vanadium(V) oxychloride

vanadium pentafluoride

sulfur trioxide

Downstream raw materials:

magnesium fluoride

(diphenyl-λ4-sulfanylidene) difluorooxovanadium(V)

(Ph₄P)[V(S₂C₂Et₂)3