Vanadium oxytrichloride

Base Information

• Chemical Name: Vanadium oxytrichloride
• CAS No.: 7727-18-6
• Deprecated CAS: 204864-21-1
• Molecular Formula: Cl3O V
• Molecular Weight: 173.3
• European Community (EC) Number: 231-780-2
• UN Number: 2443
• DSSTox Substance ID: DTXSID7064784
• Wikipedia: Vanadium oxytrichloride,Vanadium_oxytrichloride
• Wikidata: Q421166
• Mol file: 7727-18-6.mol

Synonyms:trichlorooxo vanadium;vanadium oxychloride (VOC13)

Chemical Property of Vanadium oxytrichloride

Chemical Property:

• Appearance/Colour: Yellow to brown liquid
• Vapor Pressure: 13.8 mm Hg ( 20 °C)
• Melting Point: -76.5 C
• Refractive Index: 1.6300
• Boiling Point: 126 - 127 C
• Flash Point: 126-127°C
• PSA: 17.07000
• Density: 1.84
• LogP: 1.94970
• Sensitive.: Moisture Sensitive
• Solubility.: Miscible with benzene, dichloromethane and hexane.
• Water Solubility.: decomposes in H2O to vanadic acid and HCl; soluble methanol, ether, acetone, acids [KIR83] [MER06]
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 174.868905
• Heavy Atom Count: 5
• Complexity: 6.9
• Transport DOT Label: Corrosive

Purity/Quality:

99.9% ^*data from raw suppliers

Vanadium(V) trichloride oxide, min. 99% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 14-25-34
• Safety Statements: 26-27-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: O=[V].Cl.Cl.Cl
• Uses: Vanadium(V) trichloride oxide is used as a catalyst in olefin polymerization reaction, especially for the production of ethylene-propylene rubber. It is also used to synthesis organovanadium compounds and as a mordant in dyeing. It acts as a precursor to prepare vanadium pentoxide, vanadyl dichloride and dioxovanadium monochloride. Further, it serves as a reagent and a strong oxidizing agent in organic synthesis. Catalyst in olefin polymerization (ethylenepropylene rubber) organovanadium synthesis.

Technology Process of Vanadium oxytrichloride

There total 66 articles about Vanadium oxytrichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

vanadia → vanadium(V) oxychloride (7727-18-6)

Guidance literature:

With chlorine; In neat (no solvent); heating in a flow of Cl2 at various temps. and reaction times; 99% yield after 50 min. at 680 °C;; Kinetics;

Reference yield: 74.0%

thionyl chloride (7719-09-7) + vanadia → vanadium(V) oxychloride (7727-18-6)

Guidance literature:

In neat (no solvent); heating (excess SOCl2);;

Reference yield: 70.0%

vanadia + chlorine (7782-50-5) → vanadium(V) oxychloride (7727-18-6)

Guidance literature:

With coal powder; In neat (no solvent); distn.;;

upstream raw materials:

benzoyl chloride

vanadium(II) oxide

chlorine

aluminium trichloride

Downstream raw materials:

hydrogenchloride

pyrosulfuryl chloride

vanadyl (V) chloride azide

chlorine

Refernces

• 1、 Scott, A. F.,Johnson, C. R.. "". . p. 2638 - 2648. Retrieved 1930.
• 2、 Miller, F. A.,Cousins, L. R.. "". . p. 329 - 331. Retrieved 1957.
• 3、 Dzyuba, Valeriy I.,Koval, Lyudmila I.,Shtokvysh, Olherd O.,Trachevskii, Volodymyr V.,Pekhnyo, Vasyl I.. "Lipophilic chloro-oxo-bis(hydroxamato)vanadium(V) complexes: synthesis methods and structure". . . Retrieved 2020/02/11.
• 4、 Tamai, Tsukasa,Inazu, Koji,Aika, Ken-Ichi. "Decomposition of dichlorodifluoromethane with simultaneous halogen fixation by vanadium oxide supported on magnesium oxide". . p. 1565 - 1574. Retrieved 2007/10/03.