POTASSIUM PENTACHLORONITROSYLIRIDATE(III)

Base Information

• Chemical Name: POTASSIUM PENTACHLORONITROSYLIRIDATE(III)
• CAS No.: 22594-86-1
• Molecular Formula: Cl₅IrNO*K
• Molecular Weight: 438.589
• Mol file: 22594-86-1.mol

Synonyms:Iridate(1-),pentachloronitrosyl-, potassium (8CI); Potassium pentachloronitrosyliridate(1-)

Chemical Property of POTASSIUM PENTACHLORONITROSYLIRIDATE(III)

Chemical Property:

• Melting Point: 200 °C (dec.)(lit.)
• PSA: 29.43000
• LogP: 3.66460

Purity/Quality:

98%Min ^*data from raw suppliers

Potassium pentachloronitrosyl iridium(III), 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of POTASSIUM PENTACHLORONITROSYLIRIDATE(III)

There total 1 articles about POTASSIUM PENTACHLORONITROSYLIRIDATE(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium (15)N-nitrite (68378-96-1) + potassium hexachloroiridate(III) → K(1+)*[IrCl5((15)NO)](1-)=K[IrCl5((15)NO)] (880137-03-1,22594-86-1)

Guidance literature:

In not given; according to Bottomley F., et al., J. Chem. Soc., Dalton Trans., 1974, 21, 2344;

DOI:10.1021/om700985h

Reference yield: 50.0%

potassium pentachloronitrosyl iridate(III) (22594-86-1) + acetonitrile (75-05-8,26809-02-9) + Cyclopropylamine (765-30-0) → K(H3N-cyclopropyl)[IrCl5(N-nitrosocyclopropylamine)] + K(H3N-cyclopropyl)[IrCl5(CH3CN)]*99CH3CN

Guidance literature:

In acetonitrile; byproducts: N2, cyclopropyl alcohol; (Ar); std. Schlenk technique; amine was added to was added to soln. of Ir complex in CH3CN at room temp.; centrifuged;

DOI:10.1021/om700985h

Reference yield:

K(1+)*[IrCl5((15)NO)](1-)=K[IrCl5((15)NO)] (880137-03-1,22594-86-1) + p-toluidine (106-49-0,12221-03-3) → K(1+)*IrCl5(15)NONHC6H4CH3(1-)=KIrCl5(15)NONHC6H4CH3

Guidance literature:

In not given;

DOI:10.1021/om050457n

upstream raw materials:

sodium ⁽¹⁵⁾N-nitrite

Refernces