Geranylgeranylhydroquinone

Base Information

Chemical Name:Geranylgeranylhydroquinone
CAS No.:39703-09-8
Molecular Formula:C26H38O2
Molecular Weight:0
Hs Code.:
Nikkaji Number:J2.118.325C,J248.059J
Metabolomics Workbench ID:108773
ChEMBL ID:CHEMBL479513
Mol file:39703-09-8.mol

Synonyms:2-geranylgeranyl-1,4-dihydroxybenzene;geranylgeranylhydroquinone;geranylgeranylhydroquinone, parent

Suppliers and Price of Geranylgeranylhydroquinone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Geranylgeranylhydroquinone

Chemical Property:

Vapor Pressure:6.46E-12mmHg at 25°C
Boiling Point:531.6°C at 760 mmHg
Flash Point:224.9°C
PSA：40.46000
Density:0.981g/cm³
LogP:7.78600
XLogP3:8.7
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:11
Exact Mass:382.287180451
Heavy Atom Count:28
Complexity:561

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=CCCC(=CCCC(=CCCC(=CCC1=C(C=CC(=C1)O)O)C)C)C)C
Isomeric SMILES:CC(=CCC/C(=C/CC/C(=C/CC/C(=C/CC1=C(C=CC(=C1)O)O)/C)/C)/C)C

Technology Process of Geranylgeranylhydroquinone

There total 14 articles about Geranylgeranylhydroquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 39703-08-7
2-<(2E,6E,10E)-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraenyl>-1,4-benzoquinone

: 39703-09-8
2-<(2E,6E,10E)-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraenyl>-1,4-hydroquinone

Guidance literature:: With sodium dithionite; In acetone; for 0.5h; Ambient temperature;
DOI:10.1055/s-1994-25555

Reference yield:

: 24034-73-9
Geranylgeraniol

: 123-31-9,8027-02-9
hydroquinone

: 39703-09-8
2-<(2E,6E,10E)-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraenyl>-1,4-hydroquinone

Guidance literature:: With boron trifluoride diethyl etherate; In diethyl ether; at 20 ℃; for 3h;
DOI:10.1016/j.ejmech.2016.06.036

Reference yield:

: 106-28-5
Farnesol

: 39703-09-8
2-<(2E,6E,10E)-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraenyl>-1,4-hydroquinone

Guidance literature:: Multi-step reaction with 8 steps

1: 95 percent / PBr₃ / diethyl ether / -20 °C

2: 80 percent / dimethylformamide / 20 °C

3: 90 percent / t-BuOK / -5 - 0 °C

4: 90 percent / Pd(PPh₃)4 / tetrahydrofuran / 25 °C

5: 91 percent / C₆H₅SH, Cs₂CO₃ / dimethylformamide / 85 °C

6: 92 percent / LiBHEt₃ / PdCl₂(dppp) / tetrahydrofuran / 0 °C

7: (Ce(NH₄)2(NO₃)6) / acetonitrile; H₂O / 2 h / 0 °C

8: Na₂S₂O₄ / acetone / 0.5 h / 25 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium dithionite; ammonium cerium(IV) nitrate; potassium tert-butylate; phosphorus tribromide; lithium triethylborohydride; caesium carbonate; thiophenol; bis(diphenylphosphino)propanepalladium(II) dichloride; In tetrahydrofuran; diethyl ether; water; N,N-dimethyl-formamide; acetone; acetonitrile;