3-Nitrobenzoyl chloride phenyl hydrazone

Base Information

• Chemical Name: 3-Nitrobenzoyl chloride phenyl hydrazone
• CAS No.: 63614-84-6
• Molecular Formula: C13H10ClN3O2
• Molecular Weight: 275.694
• Mol file: 63614-84-6.mol

Synonyms:BRN 1843411;3-Nitrobenzoyl chloride phenyl hydrazone;63614-84-6;BENZOYL CHLORIDE, m-NITRO-, PHENYLHYDRAZONE;LS-42608

Chemical Property of 3-Nitrobenzoyl chloride phenyl hydrazone

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Boiling Point: 414.973°C at 760 mmHg
• Flash Point: 204.768°C
• PSA: 70.21000
• Density: 1.319g/cm³
• LogP: 4.20350
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 275.0461543
• Heavy Atom Count: 19
• Complexity: 337

Purity/Quality:

99% ^*data from raw suppliers

3-NITROBENZOYL CHLORIDE PHENYL HYDRAZONE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)NN=C(C2=CC(=CC=C2)[N+](=O)[O-])Cl
• Isomeric SMILES: C1=CC=C(C=C1)N/N=C(/C2=CC(=CC=C2)[N+](=O)[O-])\Cl

Technology Process of 3-Nitrobenzoyl chloride phenyl hydrazone

There total 1 articles about 3-Nitrobenzoyl chloride phenyl hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

1-(3-nitrobenzylidene)-2-phenylhydrazine (7539-23-3) → 3-nitro-N-phenylbenzohydrazonoyl chloride (63614-84-6)

Guidance literature:

With N-chloro-succinimide; dimethylsulfide; In dichloromethane; at -78 - 20 ℃;

DOI:10.1016/j.tetlet.2008.10.145

Reference yield: 96.0%

3-nitro-N-phenylbenzohydrazonoyl chloride (63614-84-6) + N-benzyloxy-α-methyl-α-bromopropionamide (1303507-75-6) → C24H22N4O4

Guidance literature:

With triethylamine; at 20 ℃; for 1.5h;

DOI:10.1039/c7ra09766b

Reference yield: 78.0%

1,3,3-Trimethyl-2-methyleneindoline (118-12-7) + 3-nitro-N-phenylbenzohydrazonoyl chloride (63614-84-6) → 1,3,3-trimethyl-5'-(3-nitrophenyl)-2'-phenyl-2',4'-dihydrospiro[indoline-2,3'-pyrazole] (1112193-97-1)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃;

DOI:10.1016/j.tetlet.2008.10.145

upstream raw materials:

1-(3-nitrobenzylidene)-2-phenylhydrazine

Downstream raw materials:

6-(3-nitro-phenyl)-2,5,5-triphenyl-2H-5λ⁵-[1,2,4,5]triazaphosphinin-3-one

4-ethoxy-3-(3-nitro-phenyl)-1-phenyl-1,4,5,6-tetrahydro-[1,2,4]diazaphosphinine 4-oxide

4-ethoxy-3-(3-nitro-phenyl)-1,6-diphenyl-1,4,5,6-tetrahydro-[1,2,4]diazaphosphinine 4-oxide

4-ethoxy-3-(3-nitro-phenyl)-1,5-diphenyl-1,4,5,6-tetrahydro-[1,2,4]diazaphosphinine 4-oxide