Undecafluorocyclohexane

Base Information

• Chemical Name: Undecafluorocyclohexane
• CAS No.: 308-24-7
• Molecular Formula: C6H F11
• Molecular Weight: 282.056
• European Community (EC) Number: 206-213-7
• NSC Number: 93888
• UNII: 262NT3XKY8
• DSSTox Substance ID: DTXSID8075384
• Nikkaji Number: J193.725A
• Wikidata: Q81985428
• Mol file: 308-24-7.mol

Synonyms:Undecafluorocyclohexane;308-24-7;Cyclohexane, undecafluoro-;1,1,2,2,3,3,4,4,5,5,6-undecafluorocyclohexane;262NT3XKY8;EINECS 206-213-7;NSC-93888;Cyclohexane, 1,1,2,2,3,3,4,4,5,5,6-undecafluoro-;NSC93888;Undecafluorcyclohexan;1H-Perfluorocyclohexane;UNII-262NT3XKY8;SCHEMBL104139;C6HF11;DTXSID8075384;C6-H-F11;MFCD00046337;NSC 93888

Chemical Property of Undecafluorocyclohexane

Chemical Property:

• Vapor Pressure: 151mmHg at 25°C
• Boiling Point: 68.6°C at 760 mmHg
• Flash Point: 2.2°C
• Density: 1.66g/cm³
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 0
• Exact Mass: 281.99025981
• Heavy Atom Count: 17
• Complexity: 299

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1(C(C(C(C(C1(F)F)(F)F)(F)F)(F)F)(F)F)F

Technology Process of Undecafluorocyclohexane

There total 13 articles about Undecafluorocyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

1H,2H-decafluorocyclohexane (2367-86-4) → undecafluorocyclohexane (308-24-7) + perfluorocyclohexane (355-68-0) + decafluorocyclohex-1-ene (355-75-9) + 2,3,3,4,4,5,5,6,6-nonafluorocyclohexene (777-97-9)

Guidance literature:

With potassium tetrafluorocobaltate; at 280 ℃; for 2h;

DOI:10.1016/S0022-1139(00)82228-9

Reference yield: 11.5%

1H,2H-octafluorocyclohex-1-ene (775-40-6) → 1H,2H-decafluorocyclohexane (2367-86-4) + undecafluorocyclohexane (308-24-7) + decafluorocyclohex-1-ene (355-75-9) + 2,3,3,4,4,5,5,6,6-nonafluorocyclohexene (777-97-9)

Guidance literature:

With potassium tetrafluorocobaltate; at 280 ℃; for 2h; Further byproducts given;

DOI:10.1016/S0022-1139(00)82228-9

Reference yield:

(+/-)-1,1,2r,3t,4,4,5c,6t-octafluoro-cyclohexane (1526-36-9,23648-95-5,65337-53-3,65337-54-4,82086-95-1) → undecafluorocyclohexane (308-24-7) + perfluorocyclohexane (355-68-0)

Guidance literature:

at 150 ℃;

upstream raw materials:

chloro-undecafluoro-cyclohexane

perfluoro isopropyl cyclohexane

toluene

docosafluoro-bicyclohexyl

Downstream raw materials:

decafluorocyclohex-1-ene

1,2-dichlorodecafluorocyclohexane

1,2-dibromo-decafluoro-cyclohexane

Refernces