Decafluorocyclohexene

Base Information

• Chemical Name: Decafluorocyclohexene
• CAS No.: 355-75-9
• Molecular Formula: C6F10
• Molecular Weight: 262.05
• Hs Code.: 2903890090
• European Community (EC) Number: 206-592-9
• NSC Number: 93779
• DSSTox Substance ID: DTXSID8074659
• Nikkaji Number: J48.233A
• Wikidata: Q81985404
• Mol file: 355-75-9.mol

Synonyms:Cyclohexene,decafluoro- (6CI,7CI,8CI,9CI);Cyclohexene,1,2,3,3,4,4,5,5,6,6-decafluoro-;NSC 93779;Perfluorocyclohexene;

Chemical Property of Decafluorocyclohexene

Chemical Property:

• Vapor Pressure: 170mmHg at 25°C
• Melting Point: -50 °C
• Refractive Index: 1.291
• Boiling Point: 65.4 °C at 760 mmHg
• PSA: 0.00000
• Density: 1.67 g/cm³
• LogP: 3.69180
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 0
• Exact Mass: 261.98403162
• Heavy Atom Count: 16
• Complexity: 316

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1(=C(C(C(C(C1(F)F)(F)F)(F)F)(F)F)F)F

Technology Process of Decafluorocyclohexene

There total 39 articles about Decafluorocyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

octafluorocyclohexa-1,4-diene (775-51-9) → decafluorocyclohex-1-ene (355-75-9)

Guidance literature:

With vanadium pentafluoride; In trichlorofluoromethane; at 25 ℃; for 0.416667h; closed tube;

DOI:10.1016/S0022-1139(00)85033-2

Reference yield: 89.03%

Hexafluorobenzene (392-56-3) → decafluorocyclohex-1-ene (355-75-9) + perfluoro-1,3-cyclohexadiene (377-70-8)

Guidance literature:

With 1% CoF2/MgF2; fluorine; at 80 - 350 ℃; Inert atmosphere of nitrogen;

Reference yield: 83.0%

perfluoro-1,3-cyclohexadiene (377-70-8) → decafluorocyclohex-1-ene (355-75-9)

Guidance literature:

With vanadium pentafluoride; In trichlorofluoromethane; at -25 ℃; for 0.25h;

DOI:10.1016/S0022-1139(00)85033-2

upstream raw materials:

undecafluorocyclohexane

1,2,2,3,3,4,4,5,5,6,6-perfluorocyclohexanecarboxylic acid

quinoline

Hexafluorobenzene

Downstream raw materials:

2'-deoxyuridine

deoxy-5-(peerfluorocyclohexen-1-yl)uridine

5-Trimethylsilyl-2'-deoxy-β-uridine

3-(2-bromoethoxy)nonafluorocyclohexene

Refernces

• 1、 -. "Preparation method of halogenation cycloolefin". Paragraph 0066; 0067. . Retrieved 2019/08/20.
• 2、 Koppe, Karsten,Haner, Jamie,Mercier, Hlne P. A.,Frohn, Hermann-J.,Schrobilgen, Gary J.. "Xenon(IV)-carbon bond of [C6F5XeF2]+; Structural characterization and bonding of [C6F5XeF2][BF4], [C6F5XeF2][BF4]·2HF, and [C6F5XeF2][BF4]· n NCCH 3 (n = 1, 2); And the fluorinating properties of [C6F5XeF2][BF4]". . p. 11640 - 11661. Retrieved 2015/01/16.