1-nitro-4-nitrosobenzene

Base Information

• Chemical Name: 1-nitro-4-nitrosobenzene
• CAS No.: 4485-08-9
• Molecular Formula: C6H4N2O3
• Molecular Weight: 152.109
• Hs Code.: 2904209090
• Mol file: 4485-08-9.mol

Synonyms:Benzene, 1-nitro-4-nitroso-;

Chemical Property of 1-nitro-4-nitrosobenzene

Chemical Property:

• Vapor Pressure: 0.00307mmHg at 25°C
• Boiling Point: 293.2°C at 760 mmHg
• Flash Point: 131.1°C
• PSA: 75.25000
• Density: 1.41g/cm³
• LogP: 2.51590

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-nitro-4-nitrosobenzene

There total 23 articles about 1-nitro-4-nitrosobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

4-nitro-aniline (100-01-6,104810-17-5) → 4-nitrosonitrobenzene (4485-08-9)

Guidance literature:

With potassium peroxymonosulfate sulfate; In dichloromethane; water; at 20 ℃; Inert atmosphere;

DOI:10.1021/jacs.9b06998

Reference yield: 97.0%

4-Nitro-N-phenylhydroxylamine (16169-16-7) → 4-nitrosonitrobenzene (4485-08-9)

Guidance literature:

With tert-butylhypochlorite; In diethyl ether; at -78 - -20 ℃;

DOI:10.1021/jo990235x

Reference yield: 95.0%

4-Nitro-N-phenylhydroxylamine (16169-16-7) + C11H14N2O4 (88867-70-3) → 4-nitrosonitrobenzene (4485-08-9) + 4-nitro-aniline (100-01-6,104810-17-5)

Guidance literature:

With iron(II) chloride; In water; acetonitrile; at 40 ℃; pH=4.7, ionic strength=0.5 M;

DOI:10.1016/S0040-4039(00)99615-1

upstream raw materials:

para-dinitrobenzene

peracetic acid

4-nitro-aniline

Nitrosobenzene

Downstream raw materials:

2-methyl-6-(4-nitro-phenylazo)-benzothiazole

4-nitrophenyl azide

4,4'-dinitroazoxybenzene

4,4'-dinitro stilbene

Refernces

• 1、 Fúster Fernández, Inés,Hecquet, Laurence,Fessner, Wolf-Dieter. "Transketolase Catalyzed Synthesis of N-Aryl Hydroxamic Acids". . p. 612 - 621. Retrieved 2021/12/08.
• 2、 Buma, Wybren Jan,Crespi, Stefano,Di Donato, Mariangela,Doria, Sandra,Feringa, Ben L.,Hilbers, Michiel F.,Kiss, Ferdinand L.,Simeth, Nadja A.,Stindt, Charlotte N.,Szymański, Wiktor,Toyoda, Ryojun,Wesseling, Sammo. "Phenylimino Indolinone: A Green-Light-Responsive T-Type Photoswitch Exhibiting Negative Photochromism". supporting information. p. 25290 - 25295. Retrieved 2021/10/25.