Angelic Acid Methyl Ester

Base Information

Chemical Name:Angelic Acid Methyl Ester
CAS No.:5953-76-4
Molecular Formula:C6H10O2
Molecular Weight:114.144
Hs Code.:2916190090
European Community (EC) Number:227-718-9
NSC Number:55277
DSSTox Substance ID:DTXSID001302312
Nikkaji Number:J24.714F
ChEMBL ID:CHEMBL298987
Mol file:5953-76-4.mol

Synonyms:Angelic Acid Methyl Ester;5953-76-4;Methyl angelate;ANGELICACIDMETHYLESTER;methyl (Z)-2-methylbut-2-enoate;Methyl 2-methylisocrotonate;(Z)-methyl 2-methylbut-2-enoate;Methyl (E)-2-methyl-2-butenoate;EINECS 227-718-9;(Z)-2-Methyl-2-butenoic Acid Methyl Ester;Methyl (2E)-2-methyl-2-butenoate;2-Butenoic acid, 2-methyl-, methyl ester, (2E)-;SCHEMBL432847;CHEMBL298987;DTXSID001302312;Methyl (Z)-2-Methyl-2-butenoate;NSC55277;Methyl (2Z)-2-methyl-2-butenoate;MFCD00063645;NSC-55277;2-Methylisocrotonic Acid Methyl Ester;Methyl .alpha.-methylcrotonate, trans-;BS-23473;2-Methylcrotonic acid, methyl ester, (E)-;A1126;(Z)-2-Methyl-but-2-enoic acid methyl ester;trans-2,3-Dimethylacrylic acid, methyl ester;D88382;Crotonic acid, 2-methyl-, methyl ester, (Z)-;2-Butenoic acid, 2-methyl-, methyl ester, (Z)-

Suppliers and Price of Angelic Acid Methyl Ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
AngelicAcidMethylEster
5g
$ 1320.00

TCI Chemical
Methyl Angelate >97.0%(GC)
25mL
$ 148.00

American Custom Chemicals Corporation
ANGELIC ACID METHYL ESTER 95.00%
25ML
$ 1109.96

AK Scientific
Angelicacidmethylester
25ml
$ 267.00

Total 21 raw suppliers

Chemical Property of Angelic Acid Methyl Ester

Chemical Property:

Vapor Pressure:13.4mmHg at 25°C
Refractive Index:1.42
Boiling Point:123.4 °C at 760 mmHg
Flash Point:35 °C
PSA：26.30000
Density:0.916 g/cm³
LogP:1.12560
Storage Temp.:0-10°C
Solubility.:soluble in Methanol
XLogP3:1.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:114.068079557
Heavy Atom Count:8
Complexity:114

Purity/Quality:

98% ^*data from raw suppliers

AngelicAcidMethylEster ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 10
Safety Statements: 16

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC=C(C)C(=O)OC
Isomeric SMILES:C/C=C(/C)\C(=O)OC
Uses Angelic Acid Methyl Ester is a reactant in the synthesis of natural (-)-Evoninic acid.

Technology Process of Angelic Acid Methyl Ester

There total 11 articles about Angelic Acid Methyl Ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 6117-22-2
3-methyl-3-methoxycarbonyl-4,5-dihydro-1H-pyrazole

: 5953-76-4
methyl angelate

: 6622-76-0
methyl (E)-2-methyl-2-butenoate

: 51747-33-2
methyl 2-methyl-3-butenoate

: 6206-25-3
methyl 1-methylcyclopropanecarboxylate

Guidance literature:: at 155 ℃; for 20h;
DOI:10.1021/jo00142a013

Reference yield:

: 565-63-9
Angelic acid

: 18107-18-1
diazomethyl-trimethyl-silane

: 5953-76-4
methyl angelate

Guidance literature:: In diethyl ether; at 20 ℃; for 2.91667h;

Reference yield:

: 34293-67-9
methyl 3-(R)-hydroxy-2-(S)-methylbutanoate

: 5953-76-4
methyl angelate

Guidance literature:: Multi-step reaction with 2 steps

2: NaOH / methanol

With sodium hydroxide; In methanol;
DOI:10.1016/S0040-4039(00)98279-0