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Phenylmagnesium chloride

Base Information Edit
  • Chemical Name:Phenylmagnesium chloride
  • CAS No.:100-59-4
  • Molecular Formula:C6H5ClMg
  • Molecular Weight:136.864
  • Hs Code.:29319090
  • European Community (EC) Number:202-868-8
  • DSSTox Substance ID:DTXSID8059215
  • Mol file:100-59-4.mol
Phenylmagnesium chloride

Synonyms:PHENYLMAGNESIUM CHLORIDE;100-59-4;Magnesium, chlorophenyl-;Chlorophenylmagnesium;MFCD00000464;phenyl magnesium chloride;UNII-739Y484F5H;HSDB 5336;EINECS 202-868-8;Phenylmagnesium Chloride, 1.0 M in 2-MeTHF;EC 202-868-8;C6H5ClMg;C6-H5-Cl-Mg;phenylmagnesiumchloride;phenyl-magnesium chloride;PhMgCl;PHENYLMAGNESIU;chloro(phenyl)magnesium;SCHEMBL1486;DTXSID8059215;CHEBI:51490;GQONLASZRVFGHI-UHFFFAOYSA-M;AKOS009159060;739Y484F5H;Phenylmagnesium chloride, 2-3M in THF;Phenylmagnesium Chloride, 1.0 M in THF;F20531;J-802275

Suppliers and Price of Phenylmagnesium chloride
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • TRC
  • PhenylmagnesiumChloride
  • 25g
  • $ 90.00
  • TCI Chemical
  • Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L)
  • 250g
  • $ 100.00
  • Strem Chemicals
  • Phenylmagnesium chloride, 2-3M in THF
  • 1mole
  • $ 106.00
  • Strem Chemicals
  • Phenylmagnesium chloride, 2-3M in THF
  • 0.25mole
  • $ 38.00
  • Sigma-Aldrich
  • Phenylmagnesium chloride solution 2.0 M in THF
  • 100ml
  • $ 64.50
  • Sigma-Aldrich
  • Phenylmagnesium chloride solution 1.0 M in 2-methyltetrahydrofuran
  • 100ml
  • $ 48.30
  • Sigma-Aldrich
  • Phenylmagnesium chloride solution 2.0M in THF
  • 200ml
  • $ 149.00
  • Sigma-Aldrich
  • Phenylmagnesium chloride solution 2.0 M in THF
  • 800ml
  • $ 227.00
  • Sigma-Aldrich
  • Phenylmagnesium chloride solution 1.0 M in 2-methyltetrahydrofuran
  • 800ml
  • $ 215.00
  • Sigma-Aldrich
  • Phenylmagnesium chloride solution 2.0?M in THF
  • 18 L
  • $ 3790.00
Total 84 raw suppliers
Chemical Property of Phenylmagnesium chloride Edit
Chemical Property:
  • Appearance/Colour:yellowish-brown to dark brown solution 
  • Vapor Pressure:101mmHg at 25°C 
  • Melting Point:89-90oC 
  • Boiling Point:78.8oC at 760mmHg 
  • Flash Point:1°F 
  • PSA:0.00000 
  • Density:0.98 g/mL at 20 °C 
  • LogP:2.17630 
  • Storage Temp.:water-free area 
  • Sensitive.:Air & Moisture Sensitive 
  • Water Solubility.:It reacts violently with water. 
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:2
  • Rotatable Bond Count:0
  • Exact Mass:135.9930195
  • Heavy Atom Count:8
  • Complexity:100
Purity/Quality:

99% *data from raw suppliers

PhenylmagnesiumChloride *data from reagent suppliers

Safty Information:
  • Pictogram(s): FlammableF, Corrosive
  • Hazard Codes:F,C 
  • Statements: 14-19-20/21/22-34-67-65-63-48/20-11-40-37 
  • Safety Statements: 26-36/37/39-45-62-33-16 
MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:
  • Chemical Classes:Metals -> Metals, Organic Compounds
  • Canonical SMILES:C1=CC=[C-]C=C1.[Mg+2].[Cl-]
  • Uses In organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes. Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (?)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl3) in the rechargeable magnesium batteries. Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Technology Process of Phenylmagnesium chloride

There total 3 articles about Phenylmagnesium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With magnesium; In tetrahydrofuran; at 45 - 60 ℃; for 5h;
Guidance literature:
In tetrahydrofuran;
Guidance literature:
With isopropylmagnesium chloride; In tetrahydrofuran; at 0 - 10 ℃; for 0.916667h; Inert atmosphere;
DOI:10.1021/op060145b
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