Methyl 11-(chlorodimethylsilyl)undecanoate

Base Information

• Chemical Name: Methyl 11-(chlorodimethylsilyl)undecanoate
• CAS No.: 53749-38-5
• Molecular Formula: C₁₄H₂₉ClO₂Si
• Molecular Weight: 292.922
• Hs Code.: 2931900090
• European Community (EC) Number: 696-025-5
• DSSTox Substance ID: DTXSID00202022
• Nikkaji Number: J364.539H
• Wikidata: Q83075275
• Mol file: 53749-38-5.mol

Synonyms:53749-38-5;Methyl 11-(chlorodimethylsilyl)undecanoate;(10-carbomethoxydecyl)dimethylchlorosilane;10-(carbomethoxy)decyldimethylchlorosilane;methyl 11-[chloro(dimethyl)silyl]undecanoate;Undecanoic acid, 11-(chlorodimethylsilyl)-, methyl ester;C14H29ClO2Si;SCHEMBL395407;C14-H29-Cl-O2-Si;DTXSID00202022;MFCD00054817;10-(carbomethoxy)decyl dimethylchlorosilane;10-(Carbomethoxy)decyldimethyl-chlorosilane;LS-158413;11-(Chlorodimethylsilyl)undecanoic acid methyl ester

Chemical Property of Methyl 11-(chlorodimethylsilyl)undecanoate

Chemical Property:

• Vapor Pressure: 0.000189mmHg at 25°C
• Refractive Index: 1.4483
• Boiling Point: 328.5°Cat760mmHg
• Flash Point: 152.4°C
• PSA: 26.30000
• Density: 0.944g/cm³
• LogP: 5.11420
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 292.1625344
• Heavy Atom Count: 18
• Complexity: 220

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Statements: 34-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)CCCCCCCCCC[Si](C)(C)Cl

Technology Process of Methyl 11-(chlorodimethylsilyl)undecanoate

There total 2 articles about Methyl 11-(chlorodimethylsilyl)undecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethylmonochlorosilane (1066-35-9) + Methyl 10-undecenoate (111-81-9) → methyl 11-chlorodimethylsilylundecanoate (53749-38-5)

Guidance literature:

With platinum⁽⁰⁾-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; at 50 ℃; for 12h; Inert atmosphere;

DOI:10.1002/anie.201606282

Reference yield:

→ methyl 11-chlorodimethylsilylundecanoate (53749-38-5)

Guidance literature:

10-Undecensaeuremethylester, ClSiH(CH3)2;

upstream raw materials:

dimethylmonochlorosilane

Methyl 10-undecenoate