Perfluorosebacic acid

Base Information

• Chemical Name: Perfluorosebacic acid
• CAS No.: 307-78-8
• Molecular Formula: C10H2 F16 O4
• Molecular Weight: 490.0949
• Hs Code.: 29171900
• European Community (EC) Number: 626-276-8
• DSSTox Substance ID: DTXSID50184728
• Nikkaji Number: J802.692K
• Wikidata: Q81985504
• Mol file: 307-78-8.mol

Synonyms:307-78-8;Perfluorosebacic acid;Hexadecafluorosebacic acid;Hexadecafluorodecanedioic acid;Perfluorodecanedioic acid;Decanedioic acid, hexadecafluoro-;HEXADECAFLUOROSEBACICACID;2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecanedioic acid;C10H2F16O4;Decanedioic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluoro-;Hexadecafluorodecanedioic acid-5 g in glass bottle;PFLDCA n=8;SCHEMBL713583;DTXSID50184728;YPCSMEGZIYWAAZ-UHFFFAOYSA-L;MFCD00042365;AKOS015852844;C10-H2-F16-O4;FS-4248;FT-0631930;H0892;D90972;A820624;J-018135;2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecakis(fluoranyl)decanedioic acid

Chemical Property of Perfluorosebacic acid

Chemical Property:

• Appearance/Colour: white crystalline powder
• Vapor Pressure: 0.000145mmHg at 25°C
• Melting Point: 151-160 °C(lit.)
• Boiling Point: 309.2 °C at 760 mmHg
• Flash Point: 140.8 °C
• PSA: 74.60000
• Density: 1.812 g/cm³
• LogP: 4.23800
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 20
• Rotatable Bond Count: 9
• Exact Mass: 489.9697591
• Heavy Atom Count: 30
• Complexity: 651

Purity/Quality:

98%,99%, ^*data from raw suppliers

Hexadecafluorosebacic Acid ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(C(C(C(C(C(C(C(C(C(=O)O)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)O
• Uses: Reactant involved in:? ;Studies of hydrogen peroxide disproportionation kinetics of manganese phenanthroline perfluorosebacato polymeric complex1? ;Synthesis of cobalt phenanthroline perfluorosebacic acid complex2? ;Reactions with zinc salt and phenanthroline3 Reactant involved in:Studies of hydrogen peroxide disproportionation kinetics of manganese phenanthroline perfluorosebacato polymeric complexSynthesis of cobalt phenanthroline perfluorosebacic acid complexReactions with zinc salt and phenanthroline

Technology Process of Perfluorosebacic acid

There total 3 articles about Perfluorosebacic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

docosafluoro-dodeca-1,11-diene (2558-69-2) → perfluorosebacic acid (307-78-8)

Guidance literature:

With potassium permanganate; In acetone;

DOI:10.1007/BF00910110

Reference yield:

1,2-dichloro-1H,2H,6H-undecafluoro-6-iodo-hexane (812-52-2) → perfluorosebacic acid (307-78-8)

Guidance literature:

Multi-step reaction with 3 steps

1: Zn, Ac₂O / CH₂Cl₂

2: Zn, Ac₂O / acetic acid

3: aq. KMnO₄ / acetone

With potassium permanganate; acetic anhydride; zinc; In dichloromethane; acetic acid; acetone;

DOI:10.1007/BF00910110

Reference yield:

1,2,11,12-Tetrachlor-docosafluor-dodecan (2263-97-0) → perfluorosebacic acid (307-78-8)

Guidance literature:

Multi-step reaction with 2 steps

1: Zn, Ac₂O / acetic acid

2: aq. KMnO₄ / acetone

With potassium permanganate; acetic anhydride; zinc; In acetic acid; acetone;

DOI:10.1007/BF00910110

upstream raw materials:

docosafluoro-dodeca-1,11-diene

1,2-dichloro-1H,2H,6H-undecafluoro-6-iodo-hexane

1,2,11,12-Tetrachlor-docosafluor-dodecan

Downstream raw materials:

2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecane-1,10-diol

dimethyl perfluorosebacate